9a Flashcards
bromine water test
Bromine water (Br2) is initially brown as a solution and when added to a solution with a double carbon bond the bromine will join onto this molecule as the carbon molecules want to make 4 bonds.This will cause the solution to turn colourless
potassium permanganate
with a negative result:the solution stays purple because the molecules are saturated(all have single carbon bonds) and hence the potassium permanganate cannot join onto the molecule
with a positive result:unsaturated molecule present and hence the double bonds will break and the potassium permanganate will join onto the molecule turning colourless (hydroxyl groups added) with a brown precipitate(Manganese dioxide)
the two tests for unsaturated molecules
bromine water test
potassium permangenate test
hydroxyl group tests
Lucas test
acidified potassiumdichromate test
acidified potassium dichromate+silver mirror test
acidified potassium dichromate test
presence of secondary and primary alcohols and results in the reduction of the Cr 6+ to Cr3+ and this causes colour change from orange to green
silver mirror test purpose
differentiate between a primary secondary alcohol
silver mirror test
to the solution of alcohol a Tollens reagent(ammoniacal silver nitrate solution)
positive= aldehyde present= partial oxidation=primary=silver look
negative=no silver look=ketone present
Lucas test
test for presence of primary secondary and tertiary alcohol
Lucas Reagan