6- carbohydrates Flashcards

1
Q

functions of carbohydrates:

A

Provide energy for plants and animals​ (through carbohydrate oxidation)

Form supportive structures in plants (cellulose), insects and crustaceans (chitin)​

Supply short-term energy storage in plants (starch) and humans (glycogen)​

In plants: provide carbon atoms for the synthesis of other biochemical substances​ (such as proteins, lipids and nucleic acids​)

Form part of the structural framework of DNA and RNA molecules​

Act as structural components of cell membranes (when linked to lipids)

Involved in a variety of cell–cell and cell–molecule recognition processes​ (when linked to proteins)

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2
Q

Structure of carbohydrates?

A

Carbohydrates are polyhydroxy (many hydroxyl (OH) groups) aldehydes or polyhydroxy ketones, or compounds that produce such substances upon hydrolysis.

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3
Q

4 classifications of carbohydrates?

A

Monosaccharides
(Contain a single polyhydroxy aldehyde or ketone unit )

Disaccharides
(Contain 2 monosaccharide units)

Oligosaccharides
(Contains 3-10 monosaccharide units)
usually found associated with proteins and lipids in complex molecules​

Polysaccharides
(a few hundred to a few million monosaccharide units; eg cellulose, starch)

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4
Q

the smallest monosaccharides are..?

A

Trioses

as D-Glyceraldehyde​ (Aldotriose​) or Dihydroxyacetone​ (Ketotriose​)

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5
Q

the most abundant monosaccharide in nature and also the most important monosaccharide for human nutrition is..?

A

D-Glucose

it is an aldohexose

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6
Q

The normal range concentration of blood sugar is ..?

A

3.5 – 5.5 mmol/L of blood

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7
Q

What is the difference between D-glucose and D-galactose?

A

Their atoms are the same but arranged differently in space (at carbon-4)

they are both stereoisomers: have atoms bonded together in the same order

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8
Q

D-Galactose is a component of which 3 things?

A

Glycoproteins in the brain​
Glycoprotein blood group markers of the ABO blood group system​
Lactose

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9
Q

what is lactose composed of?

A

Lactose = D-Galactose + D-Glucose​

disaccharide

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10
Q

the difference between d-fructose and d-glucose?

A

fructose contains a ketone functional group​, whereas glucose contains an aldehyde functional group​

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11
Q

what is d-ribose?

A

D-Ribose​ is an aldopentose​ that functions as a vital component of important biomolecules, including nucleic acids (RNAs) and ATP​. Compared to D-Glucose, D-Ribose contains one less Carbon group.

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12
Q

Monosaccharides with 5 or more carbon atoms can exist in which 2 structures?

A

open-chain or cyclic

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13
Q

5 important reactions of monosaccharides?

A
1- Oxidation to acidic sugars ​
2- Reduction to sugar alcohols ​
3- Glycoside formation​
4- Phosphate ester formation ​
5- Amino sugar formation ​
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14
Q

what are glucoside and galactoside?

A

Glucoside​: A glycoside produced from glucose

Galactoside​: A glycoside produced from galactose

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15
Q

what is the structure of a disaccharide?

A

Disaccharides are crystalline and water-soluble substances​ that contain 2 monosaccharide units joined via a glycosidic linkage​/bond. Hydrolysis of a disaccharide produces two monosaccharides

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16
Q

D-maltose = ?​

A

D-maltose = D-glucose + D-glucose​

17
Q

what is the most abundant disaccharide?

it’s found in plants

A

D-sucrose

D-Sucrose = D-Fructose + D-Glucose​

18
Q

Oligosaccharides that occur naturally in onions, cabbage, broccoli, all types of beans and whole wheat​ include:

A

Raffinose: made of one each of galactose, glucose and fructose

Stachyose: made of 2 galactose, 1 glucose and 1 fructose units

19
Q

structure ofpolysaccharides?

A

polymers of many monosaccharide units bonded via glycosidic linkages

20
Q

Dietary carbohydrates are divided into which 2 groups?

A

Simple Carbohydrates​: Monosaccharides and disaccharides​. Simple carbohydrates are sweet-tasting and usually referred to as sugars​.

Complex Carbohydrate​: Dietary polysaccharides (starch and cellulose) that do not taste sweet​.