6- carbohydrates Flashcards
functions of carbohydrates:
Provide energy for plants and animals (through carbohydrate oxidation)
Form supportive structures in plants (cellulose), insects and crustaceans (chitin)
Supply short-term energy storage in plants (starch) and humans (glycogen)
In plants: provide carbon atoms for the synthesis of other biochemical substances (such as proteins, lipids and nucleic acids)
Form part of the structural framework of DNA and RNA molecules
Act as structural components of cell membranes (when linked to lipids)
Involved in a variety of cell–cell and cell–molecule recognition processes (when linked to proteins)
Structure of carbohydrates?
Carbohydrates are polyhydroxy (many hydroxyl (OH) groups) aldehydes or polyhydroxy ketones, or compounds that produce such substances upon hydrolysis.
4 classifications of carbohydrates?
Monosaccharides
(Contain a single polyhydroxy aldehyde or ketone unit )
Disaccharides
(Contain 2 monosaccharide units)
Oligosaccharides
(Contains 3-10 monosaccharide units)
usually found associated with proteins and lipids in complex molecules
Polysaccharides
(a few hundred to a few million monosaccharide units; eg cellulose, starch)
the smallest monosaccharides are..?
Trioses
as D-Glyceraldehyde (Aldotriose) or Dihydroxyacetone (Ketotriose)
the most abundant monosaccharide in nature and also the most important monosaccharide for human nutrition is..?
D-Glucose
it is an aldohexose
The normal range concentration of blood sugar is ..?
3.5 – 5.5 mmol/L of blood
What is the difference between D-glucose and D-galactose?
Their atoms are the same but arranged differently in space (at carbon-4)
they are both stereoisomers: have atoms bonded together in the same order
D-Galactose is a component of which 3 things?
Glycoproteins in the brain
Glycoprotein blood group markers of the ABO blood group system
Lactose
what is lactose composed of?
Lactose = D-Galactose + D-Glucose
disaccharide
the difference between d-fructose and d-glucose?
fructose contains a ketone functional group, whereas glucose contains an aldehyde functional group
what is d-ribose?
D-Ribose is an aldopentose that functions as a vital component of important biomolecules, including nucleic acids (RNAs) and ATP. Compared to D-Glucose, D-Ribose contains one less Carbon group.
Monosaccharides with 5 or more carbon atoms can exist in which 2 structures?
open-chain or cyclic
5 important reactions of monosaccharides?
1- Oxidation to acidic sugars 2- Reduction to sugar alcohols 3- Glycoside formation 4- Phosphate ester formation 5- Amino sugar formation
what are glucoside and galactoside?
Glucoside: A glycoside produced from glucose
Galactoside: A glycoside produced from galactose
what is the structure of a disaccharide?
Disaccharides are crystalline and water-soluble substances that contain 2 monosaccharide units joined via a glycosidic linkage/bond. Hydrolysis of a disaccharide produces two monosaccharides