3- Reaction rates and states of matter Flashcards

1
Q

What is energy?

A

energy is the ability to do work

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2
Q

Two classifications of energy?

A

1- Potential energy; result of position, condition, composition (chemical/nuclear)

2- Kinetic energy; because of motion (mechanical/electrical)

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3
Q

What is a reaction rate?

A

the rate at which reactants are consumed, or products are produced, in a chemical reaction

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4
Q

What determines a reaction rate?

A

The speed at which reactant(s) is/are used up​
The speed at which product(s) is/are formed​

eg Reactions which require the breaking of covalent bonds are slow and have higher activation energies.​ (ionic=faster)

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5
Q

What is activation energy?

A

the amount of energy required to activate a transformation of reactants to products

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6
Q

What occurs in an exothermic reaction?

A

energy is released as the reaction occurs

reactants have more energy than the products

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7
Q

What is an endothermic reaction?

A

energy is required for the reaction to occur (eg photosynthesis)

(Endothermic reactions occur when the energy required to break bonds in the reactants is more than the energy released by the bond formation in the products)

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8
Q

What is a catalyst in a living system?

A

Enzymes

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9
Q

Name 4 factors that affect the rate of reaction

A

1- Physical Nature of Reactants
2- Reactant Concentrations
3- Reaction Temperature
4- Presence of Catalysts

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10
Q

How does the physical nature of reactants affect a reaction?

A

A reaction will occur faster when the reactants are in the same physical state, which includes ​the physical state of each reactant (s, l, or g) and the particle size.

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11
Q

How do the reactant concentrations affect a reaction?

A

Reaction rate increases as concentration increases​ due to an increased rate of collisions

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12
Q

How does the reaction temperature affect a reaction?

A

A higher temperature provides reactant molecules with more kinetic energy and an increased molecular speed

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13
Q

How does the presence of catalysts affect a reaction?

A

The presence of catalysts in a reaction lower the activation energy, which creates a more favourable environment for the reaction to occur​.
(reaction rate increases)

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14
Q

What is a catalyst?

A

a substance that increases a chemical reaction rate without being consumed in the chemical reaction

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15
Q

How to catalysts increase reaction rates?

A

LOWERS THE ACTIVATION ENERGY = increase the reaction rate

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16
Q

What are intermolecular forces responsible for?

A

Keeping molecules together

the strength of these forces that determine if a substance will be a solid, liquid, or gas

17
Q

Name 3 types of intermolecular forces

A

1- Hydrogen bonds (not true chemical bonds)​
2- Dipole-dipole attractions​
3- Dispersion forces

18
Q

What are intramolecular forces?

A

Intramolecular forces are the bonds that hold different molecules to one another, and are referred to as the true chemical bonds​.

19
Q

Name 2 types of intramolecular forces

A

1- Ionic bonds within ionic compounds​

1- Covalent bonds within covalent compounds​

20
Q

What is the strongest type of bond?

A

Hydrogen bond

21
Q

Where do hydrogen bonds occur?

A

Hydrogen bonds occur between polar molecules within a hydrogen-containing molecule: a hydrogen atom with low electronegativity is covalently bonded to a highly electronegative element

22
Q

What are dipole-dipole attractions?

A

Attractive forces in polar molecules

eg hydrogen bond

23
Q

What are dispersion forces?

A

weak attractions between non-polar molecules​ that result from momentary uneven electron distributions within the molecules​

24
Q

What are ionic bonds?

A

strong attractive forces that hold positive and negative ions together.

25
Q

Why do ionic bonds have high melting points?

A

Because they require large amounts of energy to break apart ionic bond

26
Q

What state of matter has the highest kinetic energy?

A

Gas

27
Q

How to calculate pressure?

A

Pressure = Force / Area

28
Q

What is Boyle’s Law?

A
Boyle’s Law​ describes the pressure-volume relationship:​ as volume decreases, increases (and vice versa)
eg breathing (air moves in and out to the lower pressure region)
29
Q

What is Dalton’s Law?

A

the total pressure exerted by a mixture of gases is the sum of the partial pressures of the individual gases present​.

30
Q

What is solubility?

A

Solubility is a measure of how much of a substance will dissolve in a solvent
(like dissolves like)

31
Q

What is a saturated solution?

A

A saturated solution​ contains the maximum amount of solute that can be dissolved in the solution

32
Q

Name 3 factors that affect solubility

A

1- Size of solute particles​: Smaller particles dissolves faster​

2- The degree of mixing​: Vigorous mixing allows more solutes to dissolve

3- Temperature​: Solubility increases with an increase in temperature​

33
Q

What is Henry’s Law?

A

Henry’s Law states that the solubility of a gas is directly proportional to pressure​:

As pressure increases the gas because more soluble, dissolving more readily​
As pressure decreases the gas because less soluble, dissolving less readily​

34
Q

How does a chemical reaction occur?

A

through collisions between molecules; the faster they collide, the faster the reaction occurs