5- Introduction to organic chemistry Flashcards

1
Q

all compounds containing which 2 elements are organic compounds?

A

carbon and hydrogen

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2
Q

Name 5 organic compounds found in living organisms

A
Carbohydrates
Lipids
Proteins
Nucleic acids
Fats
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3
Q

what are hydrocarbons?

A

organic compounds containing only carbon and hydrogen atoms

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4
Q

What is the basis for the huge diversity of organic compounds?

A

The ability of carbon to form covalent bonds with other elements, for example, H, O, N, S, and itself

Each carbon has 4 unpaired electrons in its valence shell, each can be involved in one covalent bond. Total covalent bonds formed by a carbon atom is four.

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5
Q

what is the molecular formula?

A

The number and types of atoms present in a molecule but contains no information about their arrangement

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6
Q

what is the structural formula?

A

The number and types of atoms present in a molecule written in their arrangement
(CH3CH2CH3)

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7
Q

Saturated Hydrocarbons:

A

Have only single covalent bonds between C atoms
Are saturated with hydrogen TOMA
Alkane: Propane
Chemical Formula: C3H8 → CH3CH2CH3

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8
Q

Unsaturated Hydrocarbons:

A

Have 1 or more double or triple covalent bonds between C atoms
Alkene: Propene
Chemical formula: C3H6 → CH2CHCH3
Extra carbon-carbon= two fewer hydrogens in structure

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9
Q

what is the simplest functional group?

A

Alkanes

saturated hydrocarbons, meaning they had only single carbon-carbon bonds

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10
Q

what are cycloalkanes?

A

cyclic saturated hydrocarbons.

They are carbon atoms arranged into a closed ring structure and a density lower than water

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11
Q

what are prefix cyclos?

A

the rings found in nature size from 3-30 carbon atoms

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12
Q

what is halogenation?

A

the direct reaction with halogens (chlorine, bromine, iodine).
Substitution of one or more of the H-atoms of hydrocarbons by halogen atoms, producing haloalkanes or halocycloalkanes

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13
Q

what are halogenated alkanes?

A

Derivatives alkanes in which one or more hydrogen atoms are substituted by halogen atoms

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14
Q

what are halogenated cycloalkanes?

A

Cycloalkane derivatives in which one or more hydrogen atoms are substituted by halogen atoms​. These derivatives are named as:​

Haloalkanes or Halocycloalkanes (IUPAC naming)​
Alkyl halides or Cycloalkyl halides (common naming)

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15
Q

what is an alkene?

A

An alkene is an acyclic unsaturated hydrocarbon that contains one or more carbon-carbon double bonds

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16
Q

what do names that end with an “-ene” mean?

A

a double bond is present

17
Q

the difference between hydrogenation and halogenation of alkenes?

A

hydrogenation - a hydrogen atom is added to each carbon atom of a double bond or triple bond and a catalyst such as Pt or Ni is used to speed up the reaction

halogenation - a halogen atom is added and no catalyst is needed

18
Q

what are polymers?

A

macromolecules (huge molecules) in which small units (monomers) are repeated again and again.​

19
Q

polymers are:

A

Large, long-chain molecules.​
Found in nature, including cellulose in plants, starches in food, proteins and DNA in the body.​
Also synthetic, such as polyethylene and polystyrene, Teflon, and nylon.​
Made up of small repeating units called monomers.​
Made by reaction of small alkenes.​
In polymerization, small repeating units called monomers join to form a long chain polymer

20
Q

alkynes are..?

A

unsaturated hydrocarbons containing one or more triple bonds

21
Q

what is the structure of aromatic hydrocarbons (arenes)?

A

they contain a benzene ring with alternate double and single bonds. Double bonds are different thank alkenes, these are called delocalised.

Features:

Insoluble in water​
Soluble in non-polar solvents like hydrocarbons, etc. ​
Less dense than water, therefore, floats on water​
Benzene is colourless, flammable liquid burns with a sooty flame​
Petroleum is the primary source of aromatic hydrocarbons​
Gasoline has a significant amount of benzene in it

22
Q

The compound that contains the ring structure of benzene is called?

A

an aromatic compound

23
Q

Alcohol is part of which functional group?

A

Hydroxyl

The general formula is R-OH
An alcohol contains a hydroxyl group (-OH) attached to a carbon chain.

24
Q

Where do oxidation reactions of alcohols happen in the body? (as they break down)

A

In the liver in the form of ethanol

25
Q

2 properties of phenols?

A

antioxidant and antiseptic

Phenol​s is an organic compound in which an -OH group is attached to a carbon atom that is part of an aromatic carbon ring system

26
Q

what is the functional group of ethers?

A

oxygen within a carbon chain -O-.

The general forumla is R-O-R.

The IUPAC name is alocy alkane. Ethers consist of an oxygen atom that is connected by single bonds to two carbon groups (alkyl or aromatic

27
Q

the most common aldehyde?

A

methanal (formaldehyde)

28
Q

Chemical properties of Aldehydes and Ketones

A

Aldehydes readily oxidise to carboxylic acids, whilst ketones resist oxidation.

The carboxylic acids from aldehydes are utliised in the breakdown of alcohol.

As ketones resist oxidation, they are unreactive