5.2 Redox Flashcards
What are the steps to balance half equations?
1) balance atoms apart from O and H
2) add H2O to balance Os
3) add H+ to balance Hs
4) balance charges (e.g. 4H+ = charge 4+)
What are standard conditions?
298K
100kPa
1M solution
What does emf stand for?
Electromotive force
How is emf calculated?
The more positive potential - the more negative potential
The more positive the potential…
… The more spontaneous in favourable the reaction
Limitations of emf
It does not take kinetics into account.
Even?
If a reaction is thermodynamically feasible, it may occur at such a slow rate that it does not actually occur
It also relies on standard conditions being maintained throughout a reaction where in reality the system may deviate
If the overall potential value is positive…
… A disproportionation reaction is feasible
If the overall potential value is positive…
… A disproportionation reaction is feasible
If the overall potential value is positive…
… A disproportionation reaction is feasible