4.1 Flashcards

1
Q

Homologous series

A

A series of organic compounds that have the same functional group with successive members differing by CH2

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2
Q

Aliphatic

A

A hydrocarbon with carbon atoms joined together in straight or branched chains

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3
Q

Alicyclic

A

A hydrocarbon with carbon atoms joined together in a ring structure

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4
Q

Aromatic

A

A hydrocarbon that contains at least one benzene ring

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5
Q

Saturated

A

Has only single bonds

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6
Q

Functional group

A

A group of atoms responsible for the characteristic chemical reactions of a compound

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7
Q

General formula

A

The simplest algebraic formula for a homologous series

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8
Q

Displayed formula

A

Shows the relative positions of atoms and the bonds between them

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9
Q

Structural formula

A

Provides the minimum detail for the arrangement of atoms in a molecule

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10
Q

Skeletal formula

A

Simplified structural formula drawn by removing hydrogen atoms from alkyl chains

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11
Q

Structural isomers

A

Compounds with the same molecular formula but different structural formulae

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12
Q

Stereoisomers

A

Organic compounds with the same molecular formula and structural formula but different arrangements of atoms in space

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13
Q

E/Z isomerism

A

A type of stereoisomerism caused by restricted rotation around the double bond - 2 different groups are attached to both carbon atoms of the double bond

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14
Q

Cis-trans isomerism

A

Type of E/Z isomerism in which the two substituent groups attached to both carbon atoms in the double bond are the same

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15
Q

Cahn-Ingold-Prelog rules

A

Locate the C=C double bond.
Focus on one C and assign priority of each substituent based on its relative atomic mass.
Then do the same for the second C.
If the highest priority groups are on the same side of the C=C double bond, then the isomer is Z.
If the highest priority groups are on the different sides of the C=C double bond, then the isomer is E.

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16
Q

Reaction mechanisms

A

Models that show the movement of electron pairs during a reaction

17
Q

Radicals

A

Species with one or more unpaired electrons

18
Q

Homolytic fission

A

When each bonding atom receives one electron from the bonded pair, forming 2 radicals

19
Q

Heterolytic fission

A

When one bonding atom receives both electrons from the bonding pair

20
Q

Electrophile

A

An electron pair acceptor

21
Q

Monomers

A

Small molecules used to make polymers

22
Q

Polymers

A

Macromolecules made from small repeating units

23
Q

Repeating unit

A

A specific arrangement of atoms that occurs in a structure repeatedly

24
Q

Biodegradable

A

Materials affected by the action of microorganisms and environmental conditions, leading to decomposition

25
Q

Bioplastic

A

A material made from a renewable source that it biodegradable

26
Q

Hydrogenation

A

150°C, Nickel catalyst

27
Q

Hydration

A

Steam, 300°C, 65atm, H3PO4 catalyst

28
Q

Sigma bond

A

Direct overlap of the electron clouds of the two atoms

29
Q

Pi bond

A

Formed by electrons in the adjacent p-orbitals overlapping above and below the carbon atoms

30
Q

Which isomer has kinks and a lower density and m.p - cis or trans?

A

Cis

31
Q

Markownikoff’s rule

A

When HX or H2O is added to an alkene, the H attaches to the C with the most Hs to make the more stable carbocation

32
Q

3 ways to get rid of polymer waste

A

Landfill
Combustion
Biodegration