5.2- Ionic Bonding And Structure Flashcards
Define ionic bonding
The electrostatic attraction between positive and negative ions
What is the structure of an ionic compound?
Each ion attracts oppositely charged ions in all directions that result is a giant ionic lattice structure
What happens when there is a greater charge?
Greater the charge = stronger the electrostatic force of attraction = greater energy needed to separate them =high m.p and b.p
Why do ionic compounds have high melting and boiling points?
- There are strong electrostatic forces of attraction between the oppositely charged ions in all directions which require lots of energy to overcome
- smallerions pack close together = increase the m. p and b.p
Why are ionic compounds generally soluble in water?
-Water is a polarmolecule and so the small delta positive and delta negative charges surround and add up to the opposite charge on the ion
- due to the attraction it disrupts the electrostatic forces of attraction between them and breaks them apart
What are the 2 processes that solubility requires?
- The ionic lattice must be broken down
- Water molecules must attract and surround the ions
Why do they not conduct electricity when solid?
-The ions are held together in a fixed position by strong, electrostatic forces acting in all directions
- unable to move and carry the charge
Why can they conduct electricity when molten or aqueous?
Ions are free to move and carry the charge through the structure
Why are the compounds brittle?
- when moved ions no longer have their alternating lattice arrangement
- instead ions with the same charge end up next to each other
- due to the repulsion between like charges the structure breaks apart
In what type of solvents do ionic lattices dissolvein?
Polar solvents Eg. Water