10.1-reaction Rates Flashcards
Define rate of a chemical reaction
How fast a reactant is being used up or how fast a product is being formed
Define the rate of reaction
The change in concentration of a reactant or a product in a given time
Give the formula for rate
Rate = change in concentration / time
What are the units for change in concentration ?
Mol dm ^-3
What are the units for rate
Mol dm ^-3 S^-1
What are the 4 factors that can affect a chemical reaction ?
- concentration ( or pressure when reactants are gasses )
- temperature
- use of a catalyst
- surface area of solid reactants
What does collision theory state ?
Two reacting particles must collide for a reaction to occur
What are the conditions of effective collisions ?
- the particles collide with correct orientation
- the particles have sufficient energy to overcome the activation energy barrier of the reaction
How does increasing the concentration affect the rate of reaction ?
- when the conc of a reactant is increased = ROR generally increases
- increase in concentration = increases the number of particles in the same volume
- the particles are closer together and collide more frequently
- in a given period of time there will thus be more effective collisions
- resulting in a higher rate of reaction
How does increasing the pressure of a gas affect the rate of reaction ?
- when a gas is compressed into a smaller volume the pressure of a gas is increased = ROR also increases
- the conc of the gas molecules increases as the same number of gas molecules occupy a smaller volume
- gas molecules are closer together and collide more frequently
- thus leading to a more effective collisions in the same time
What are the methods for following the progress of a reaction ?
- monitoring the decrease in concentration of a reactant
- following the increase in concentration of a product
What does the method chosen depend on ?
- depends on the properties and physical states of the reactants and products In the reaction
- gas volume
- mass of reactants
- colour
- mass of products
How to monitor reactions that produce gases ?
- monitor the volume of gas produced at a regular time intervals using gas collection
- monitoring the loss of mass of reactants using a balance
What is the relevance of volume of gas and mass lost ?
They are both proportional to the change in concentration of a reactant or product