5) ESTERS, FATS & OILS Flashcards

1
Q

What are esters made from

A

Carboxylic acid and alcohol

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2
Q

What type of reaction is making an esters

A

Condensation

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3
Q

What do you get when you break up an ester

A

Carboxylic acid and alcohol

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4
Q

What type of reaction is breaking up an ester

A

Hydrolysis

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5
Q

Is making an ester reversible or non reversible

A

Reversible

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6
Q

What is used to keep an ester from breaking up

A

A strong acid catalyst such as concentrated sulphuric acid

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7
Q

Where do the OH and H come from in the formation of an ester

A

OH from Carboxylic acid

H from alcohol

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8
Q

What else is given out during the formation of an ester

A

Water

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9
Q

What type of catalyst is used in the hydrolysis of an ester

A

An alkali catalyst such as sodium hydroxide solution

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10
Q

Uses of esters

A

Flavourings:
Fruits, artificial flavours

Fragrances:
Perfumes, deodorants

Non polar solvents:
Nail polish remover

Medicine:
Antibiotics

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11
Q

What are fats and oils

A

Esters

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12
Q

How are fats an oils formed

A

When 3 fatty acids join with glycerol in a condensation reaction

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13
Q

Where does the H and OH come from in the formation of an ester

A

OH from glycerol

H from acid

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14
Q

What is else is formed in the formation of an fat or oil

A

Water

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15
Q

Why are fats solid at room temperature where as oils are liquids

A
  • Fats don’t have double bonds.
  • As there are no links in the structure the fat can pack closely together.
  • This causes stronger LDF’s between fat molecules.
  • Stronger LDF’s means more energy to separate which results in a higher MP
  • Oils have double bonds.
  • The double bonds causes links in the structure of the oil.
  • The oil molecules therefore cannot pack as closely together causing weaker LDF’s between oil molecules.
  • Lower LDF’s means less energy to separate which results in a lower MP
Mention:
Double bonds
Kinks
Packing
LDF's
Energy to separate
Melting points
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16
Q

What are essential oils

A

Volatile, unsoluable, aromatic compounds found in plants

17
Q

Uses of essential oils

A
  • perfumes
  • cleaning products
  • flavourings
18
Q

How are essential oils usually extracted

A
Distillation (using steam)
Solvent extraction (like the caffeine from coffee)
19
Q

What makes up essential oils

A

Terpenes

20
Q

What are terpenes made up of

A

Isoprene units

21
Q

What is a key property of terpenes

A

They are very aromatic as they are volatile

22
Q

Systematic name of an isoprene unit

A

2 methyl buta - 1, 3 - diene

23
Q

Systematic name for glycerol

A

Propan - 1,2,3 - triol