4.3 HALOGENS Flashcards

1
Q

how are the elements bonded?

A
  • covalently bonded
  • simple molecular substances
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2
Q

properties of group 7 elements:

A
  • all diatomic
  • colours get darker down the group
  • melting/ boiling point increases down the group
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3
Q

colour of fluorine:

A
  • F2
  • very pale yellow
  • gas
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4
Q

colour of chlorine:

A
  • Cl2
  • pale green
  • gas
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5
Q

colour of bromine:

A
  • Br2
  • brown
  • liquid
  • volatile
  • releases brown fumes
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6
Q

colour of iodine:

A
  • I2
  • dark grey
  • solid
  • sublimes
  • releases purple fumes
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7
Q

colour of astatine:

A
  • At2
  • black
  • solid
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8
Q

what do halogens form when they react with metals?

A

ionic compounds

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9
Q

what happens to reactivity as you go down the group?

A

get less reactive

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10
Q

why do the halogens get less reactive as you move further down the series?

A
  • all halogen atoms need to gain an electron to fill their outer shell
  • this happens less easily as you go down the group because:
  • atoms have more electron shells
  • the extra electron is further from the nucleus
  • so its attraction to the nucleus is weaker
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11
Q

test for chlorine:

A

damp blue litmus paper turns white because chlorine acts as a bleaching agent

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12
Q

what do hydrogen and chlorine react to form?

A

hydrogen chloride (colourless)

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13
Q

why does the reaction of hydrogen and chlorine produce a colour change?

A
  • due to the substances involved
  • HCl is a covalently bonded, simple molecular substance
  • it is a gas because it has a low boiling point due to weak IMFs
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14
Q

what happens when you dissolve HCl into water?

A
  • HCl (g) dissolves to form HCl (aq)
  • HCl (aq) dissociates to form H+ (aq)
  • the H+ (aq) is acidic
  • HCl (aq) is called hydrochloric acid
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15
Q

what happens when you dissolve HCl into methylbenzene?

A
  • HCl (g) dissolves to form HCl (org)
  • HCl (org) cannot dissociate
  • there is no H+ (org)
  • HCl (org) is not acidic
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16
Q

what is a displacement reaction?

A

more reactive halogens can displace less reactive halogens from their compounds

17
Q

what colours are aqueous halogens Cl2, Br2 and I2?

A
  • Cl2- colourless
  • Br2- yellow
  • I2- brown
18
Q

what colours are the aqueous salts KCl, KBr, Kl?

A

all colourless

19
Q

what happens when you react KBr and Cl2?

A

Cl2 + 2KBr—> Br2 + 2KCl
- chlorine displaces bromine
- colourless —–> yellow

20
Q

what happens when you react KI and Cl2?

A

Cl2 + 2Kl—> I2 + 2KCl
- chlorine displaces iodine
- colourless—-> brown

21
Q

what happens when you react KCl and Br2?

A
  • no change
  • stays yellow
22
Q

what happens when you react KI and Br2?

A

Br2 + 2Kl—> I2 + 2KBr
- bromine displaces iodine
- yellow—-> brown

23
Q

what happens when you react KCl and I2?

A
  • no change
  • stays brown
24
Q

what happens when you react KBr and l2?

A
  • no change
  • stays brown
25
Q

what do the displacement reactions infer:

A

the reactivity trend is chlorine> bromine> iodine

26
Q

all halogen displacement reactions are…

A

redox reactions