4.3 Carbon cycling Flashcards

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1
Q

Describe the heaviness of CO2

A

Carbon dioxide, CO2, is a gas that is heavier than other components found in the atmosphere, so it will accumulate at the bottom of a room.

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2
Q

How does the sinking of CO2 affect heterotrophs? (reword)

A

-In nature, it will slowly diffuse to the lower layers of a forest or canyon, which could pose a problem for heterotrophs since CO2 is a waste product from respiration and they need to take in oxygen for survival.

-However, CO2 can be mixed in the air due to temperature changes and wind patterns.

-Since CO2 tends to sink, it is readily available to photosynthesisers and can be trapped in water.

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3
Q

Describe the solubility of carbon dioxide

A

-Carbon dioxide solubility is quite low ranging from 0.88 cm3 to 0.65 cm3 of CO2 per gram of water, with temperatures of 20 °C to 30 °C.

-However, the solubility of CO2 increases as pressure increases.

-So, if CO2 sinks, it is at a higher pressure at the water’s surface and, with waves or turbulence, can dissolve into the water to be available for aquatic plants.

-Large amounts of CO2 can be dissolved in sparkling water using pressure.

-Once you have opened a bottle of sparkling water, pressure drops and the carbon dioxide forms bubbles and escapes from the water.

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4
Q

How can carbonic acid be made and what are its properties?

A

-Carbon dioxide can combine with water to form carbonic acid (H2CO3).

-This molecule is unstable and dissociates easily in water into hydrogen ions (H+) and hydrogen carbonate ions (HCO3-).

-The H+ that are released during this dissociation lowers the pH of the water (makes it more acidic).

-This is also important when discussing the CO2 that dissolves in blood plasma.

-When CO2 combines with the water in blood it lowers the pH.

-This is detected by the brain which sends a signal for you to breathe.

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5
Q

Key info about carbonic acid

A

-Carbonic acid – H2CO3 – is the molecule that forms when CO2 combines with water.

-This molecule is unstable and dissociates easily in water into hydrogen ions (H+) and hydrogen carbonate ions (HCO3-).

-The H+ that are released in this dissociation lower the pH of the water (makes it more acidic).

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6
Q

Diagram showing how CO2 can accumulate above water, then dissolve due to pressure. It may then become carbonic acid and break down to H+ making the water more acidic

A
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7
Q

Hydrogen carbonate ions are also known as ___

A

Bicarbonate ions

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8
Q

In aquatic ecosystems, carbon is present both as ___

A

Dissolved carbon dioxide and hydrogen carbonate ions

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9
Q

In what form do aquatic plants and other autotrophs living in water require carbon and for what?

A

They require carbon in the form of dissolved carbon dioxide and hydrogen carbonate ions to produce more complex carbon compounds.

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10
Q

How do land plants and aquatic plants take up CO2 and what effect does this have?

A
  • Land plants take up carbon dioxide as a gas through their stomata, which are pores found in their leaves.
  • In aquatic plants, dissolved carbon dioxide diffuses into the leaves from the environment.
  • In both cases, in water and on land, the carbon dioxide is used in the Calvin cycle to make carbohydrates and more complex carbon compounds.
  • This lowers the concentration of carbon dioxide in the plant, setting up a concentration gradient that helps the carbon dioxide diffuse into the autotrophs.
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11
Q

What are stomata?

A

Pores found on the underside of leaves which allow for gas exchange.

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12
Q

Stomata on aquatic plants

A

Aquatic plants are adapted to have stomata on the upper side of their leaves for gas exchange.

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13
Q

Diagram of how CO2 diffuses from the atmosphere or water into autotrophs

A
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14
Q

Picture of stomata

A
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15
Q

Diagram showing what happens to carbon dioxide during photosynthesis and its interaction with heterotrophs

A
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16
Q

Taking in and release of CO2 in autotrophs and heterotrophs

A

-Autotrophs take up carbon dioxide and give off oxygen during photosynthesis.

-Heterotrophs can exist because of this process.

-However, both heterotrophs and autotrophs respire and produce carbon dioxide.

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17
Q

What process takes place in cells to produce CO2?

A

Cellular respiration takes place in cells to produce carbon dioxide, just like in all heterotrophs.

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18
Q

What organelles do plants have for photosynthesis and respiration and how do they use these?

A

-Plant cells contain chloroplasts, used for photosynthesis, as well as mitochondria, used for respiration.

-When plant cells perform aerobic respiration, mitochondria use oxygen and produce carbon dioxide.

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19
Q

How do plants use carbon dioxide during the day?

A

-During the day, carbon dioxide from respiration can be used directly by the chloroplasts for photosynthesis.

-In this case, carbon dioxide is not released from the leaves, as photosynthesis mainly occurs here.

-Carbon dioxide produced during respiration is a waste product of metabolism and diffuses out of the plant into the atmosphere or water.

-Carbon dioxide is also produced in anaerobic conditions where there is no oxygen available.

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20
Q

What are anaerobic conditions?

A

-Environmental conditions that lack oxygen for aerobic respiration.

-Also, known as anoxic conditions.

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21
Q

Diagram showing how CO2 is produced by both aerobic and anaerobic respiration

A
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22
Q

Describe the seasonal changes in CO2 concentration in Earth’s atmosphere

A

-In the northern hemisphere during the winter months, most plants are dormant because they lose many of their leaves which absorb CO2; producing little oxygen and taking up little carbon dioxide.

-So, during the cold winter season, the carbon dioxide concentration in the atmosphere increases due to less absorption from plants.

-More fuel is burnt to heat houses and the heterotrophs are still respiring.

-During spring and summer, trees will grow more leaves, which are able to absorb the atmospheric CO2, so the concentration in the atmosphere will drop.

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23
Q

The following graph shows variation in the concentration of CO2 in the atmosphere as measured at Mauna Loa in Hawaii. The small inset graph shows the variations in CO2 during the year.

Why does the concentration of CO2 decrease between April and August? Please take into account that Hawaii is located in the northern hemisphere.

A

The rate of photosynthesis in the northern hemisphere plants increases due to the summer season.

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24
Q

In aquatic ecosystems, carbon is present as ___

A

Dissolved CO2 ​and bicarbonate ions (hydrogen carbonate)

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25
Q

Which type of organisms convert atmospheric carbon dioxide into carbon compounds passed through the food chain?

A

Autotrophs

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26
Q

What is methane?

A

Methane – CH4 – is a carbon molecule that is produced in anaerobic/anoxic conditions and can oxidize into carbon dioxide and water.

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27
Q

Picture of marsh gas formations on a swamp in the Volta region in Ghana.

Marsh gas is a mix of methane and carbon dioxide.

A
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28
Q

How is methane produced?

A

-From organic matter under anaerobic conditions (meaning organisms that live without oxygen) by methanogenic archaeans (single-celled prokaryotes).

-These bacteria are found in several anoxic (without oxygen) environments, for example, wetlands, such as swamps, marshes, and bogs, as well as lake beds, the guts of ruminants, termites, and landfill sites.

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29
Q

What can happen to methane once it’s formed?

A

It may either diffuse into the atmosphere or accumulate in the ground.

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30
Q

What are methanogenic archeans?

A

Bacteria that are found in several anoxic environments and produce methane as part of the carbon cycle.

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31
Q

What are ruminants?

A

-Mammals that have a mutualistic relationship with methanogenic archaeans that help them to digest cellulose from the cell walls in the plants they eat.

-This creates methane, which is released as gas from the mammal.

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32
Q

Diagram of the chemical structure of methane

A
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33
Q

How is methane produced in ruminants?

A

The gut bacteria in ruminants and other herbivores produce vast amounts of methane, which is released into the atmosphere.

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34
Q

Diagram of methane production in herbivores

A
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35
Q

What are the types of organic matter that can be used for methane production?

A

-These include manure from farm animals and cellulose from plants.

-These are converted successively by several groups of bacteria.

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36
Q

Describe the process in which manure from farm animals and cellulose from plants is converted successively by several groups of bacteria (final step is methanogenesis)

A

-Ruminants chew on plants, breaking down the molecules, such as some carbohydrates, into smaller monomers (using their saliva) by the process of hydrolysis.

-Organic matter is first changed to organic acids and alcohol, such as ethanol, by a group of bacteria in a process called acidogenesis.

-Other bacteria then convert these organic acids and alcohol into acetate (through acetogenesis), carbon dioxide and hydrogen.

-Finally, methanogenic bacteria can produce methane either through the reaction of carbon dioxide and hydrogen (1) or through the breakdown of acetate (2), also known as methanogenesis.

-Methane can accumulate in the ground or diffuse into the atmosphere

-Methane does not build up to high levels in the atmosphere, as it is oxidized to form carbon dioxide and water

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37
Q

Chemical equations to show how methanogenic bacteria can produce methane either through the reaction of carbon dioxide and hydrogen (1) or through the breakdown of acetate (2), also known as methanogenesis

A
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38
Q

What is hydrolysis?

A

The chemical process of breaking large polymers into dimers or monomers using water.

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39
Q

What is acidogenesis?

A

The chemical process in which bacteria convert organic matter into organic acids and alcohol.

40
Q

What is acetogenesis?

A

The chemical process in which bacteria convert organic acids and alcohol into acetate.

41
Q

What is methanogenesis?

A

The chemical process in which methanogenic bacteria can produce methane through the reaction of carbon dioxide and hydrogen or through the breakdown of acetate.

42
Q

How is methane oxidized?

A

-In the upper layers of the atmosphere through the interaction of methane with hydroxyl radicals, which are highly reactive.

-The reaction produces CO2 and water.

-The complete oxidation of methane to carbon dioxide and water involves several steps and includes several intermediate compounds.

43
Q

How is methane oxidized?

A

-In the upper layers of the atmosphere through the interaction of methane with hydroxyl radicals, which are highly reactive.

-The reaction produces CO2 and water.

-The complete oxidation of methane to carbon dioxide and water involves several steps and includes several intermediate compounds.

44
Q

Explain how peat is formed

A

-In many parts of the world, dead leaf matter and other organic debris are digested by saprotrophs.

-This is an aerobic process (meaning it requires oxygen).

-However, there are some waterlogged areas where the stagnant water creates an anaerobic (no oxygen present) environment in which the saprotrophs cannot grow.

-The result is an environment that becomes progressively acidified over time. Any surviving saprotrophs die, and the remaining organic matter is only partially digested.

-New layers of leaf litter and other organic debris fall on top of this older layer of material, further compressing it.

-The result is peat.

45
Q

How deep can peat be?

A

Peat exists across wide areas of our planet and can reach depths of 10m.

46
Q

Overview of how peat forms

A

Peat forms when organic matter is not fully decomposed because of acidic and/or anaerobic conditions in waterlogged soils.

47
Q

What is peat?

A

-Partially digested organic matter that forms in acidic, water-saturated soil.

-Peat contains large amounts of carbon and can be compressed into coal over time.

48
Q

Picture of a peat-forming area

A
49
Q

What are the uses of peat?

A

-As a substitute for firewood for cooking and heating

-To increase the moisture holding capacity of the soil (that is rich in sand particles) in horticulture

-To increase the water infiltration rate of soils rich in clay particles

-To acidify soils for specific pot plants.

50
Q

How can coal form from peat?

A

If peat is covered by sediments as well as further compressed and heated over many millions of years, coal is formed.

51
Q

Explain how organic matter is decomoposed

A

-A process similar to the formation of coal from peat happens at the bottom of lakes and oceans where dead organisms decomposed.

-The anaerobic conditions that exist in these environments leave the decomposition unfinished.

-In these anaerobic conditions, saprotrophic bacteria cannot grow and decompose the decaying vegetation and organisms and the soil becomes acidic.

-The subsequent pressure and heat allow for certain chemical changes to take place.

-Over long periods of time, oil and gas are formed.

-Thus, partially decomposed organic matter from past geological eras was converted either into coal in wetlands, or into oil and gas in oceans where it accumulated in porous rocks.

52
Q

Where are the three forms of carbon-based fuels found?

A

-The three forms of carbon-based fuels are chemically stable for long periods of time.

-The fuel deposits that we use today were formed a long time ago, and that is why they are referred to as fossil fuels.

-Coal can be found in thick layers beneath the surface and is extracted through mining.

-Oil and gas are found in porous rock, although gas is not in a gaseous form.

-Gas reservoirs are found deep in the Earth under high-pressure conditions that will maintain the gas in liquid form.

53
Q

How are oil and gas extracted from the Earth?

A

They are pumped out of the Earth using oil drills and rigs.

54
Q

What are fossil fuels?

A

Organic material that has been compressed over time, to form coal, oil and gas.

55
Q

How and when was the carbon trapped in the fossil fuels removed from the atmosphere

A

Many millions of years ago by autotrophs.

56
Q

What two things combine through the process of combustion or burning?

A

Hydrocarbons found in organic compounds can be combined with oxygen to form carbon dioxide, water, and energy through the process of combustion or burning.

57
Q

What does combustion of biomass and burning of fossil fuels release?

A

Combustion of biomass and burning of fossil fuels, whether by accident, such as peat fires, or purposefully, to drive engines, releases carbon in the form of carbon dioxide back into the atmosphere.

58
Q

What is combustion?

A

A process of burning which releases CO 2 from organic material such as fossil fuels or biomass.

59
Q

In what other ways is carbon trapped in biomass released back into the atmosphere?

A

-For instance, forest fires release enormous amounts of carbon dioxide back into the atmosphere.

-As such, the combustion of any form of biomass releases carbon dioxide back into the environment, as biomass is mostly organic in nature.

-Thermal vents, such as volcanoes, fumaroles, and mazukus can also release CO 2 into the atmosphere.

60
Q

Describe the presence of calcium carbonate in nature

A

-Calcium carbonate (CaCO3) is widely found throughout nature.

-Shells of mollusks and the exoskeletons of hard corals and crustaceans contain carbon in large quantities.

-When these animals die, the calcium carbonate becomes part of the sedimentary rock if the conditions are not too acidic.

61
Q

What is calcium carbonate?

A

Calcium carbonate – CaCO3 – an important source of carbon in the environment which makes up shells and exoskeletons and can eventually become porous sedimentary rock such as limestone.

62
Q

How does calcium carbonate dissolve?

A

-Calcium carbonate dissolves in acid, but not in alkaline solutions.

-Most of our oceans are slightly alkaline, creating the right conditions for the formation of sedimentary rock such as limestone.

63
Q

How is limestone formed? (reword)

A

-Most of our oceans are slightly alkaline, creating the right conditions for the formation of sedimentary rock such as limestone.

-It is estimated that 10% of all sedimentary rock on Earth consists of limestone.

-Considering that limestone is composed of approximately 12% carbon, these limestone formations lock up a large amount of carbon.

64
Q

Writing about carbon reservoirs on Earth for the exam

A

-When asked about the carbon reservoirs on Earth, be sure to include sedimentary rocks, such as limestone deposits.

-The other reservoirs are more obvious: biomass of plants and animals including calcium carbonate shells, the atmosphere, fossil fuels, and the carbon dioxide dissolved in the oceans.

65
Q

Labeling processes that move carbon from one form to another for the exam

A

-You should be able to label the processes that take place to move carbon from one form to another.

-For example, be able to label: photosynthesis, which changes CO2 in the atmosphere into carbon compounds in plants; consumption, which moves carbon into the food chain; fossilization or lithification, which compresses carbon into rocks, fossils, or fossil fuels; and combustion and respiration, which releases carbon back into the atmosphere.

66
Q

What is lithification?

A

The process of compressing organic matter over a long period of time until it becomes rock.

67
Q

For the formation of limestone rocks from the shells of mollusks and the exoskeleton of corals, the conditions should be ___

A

Slightly alkaline

68
Q

What is limestone, a sedimentary rock, made from?

A

Calcium carbonate

Limestone is a sedimentary rock. Sedimentary rocks come from broken down shells made of calcium carbonate.

69
Q

What is a reservoir?

A

-A place where a certain element, such as carbon, has accumulated or pooled.

-Also, known as a sink when discussing nutrient cycling.

-In the case of carbon, it can be in an inorganic form, such as carbon dioxide, or it can be organic, such as the biomass of the autotrophs.

70
Q

Describe how exchanges between reservoirs occur

A

-Reservoirs are not static entities – exchanges between the carbon reservoirs occur.

-When carbon moves from one reservoir, or sink, to another it is called a flux.

-A flux can also be thought of as the process that moves the carbon from one reservoir to another.

71
Q

Give an example of a carbon flux

A

-The conversion of atmospheric carbon dioxide into glucose and other complex carbon compounds by the autotrophs.

-The flux in this example is photosynthesis.

-Or in other words; photosynthesis turns inorganic carbon into organic biomass.

-The sink in this example is the autotroph because now the carbon is locked up in the organism itself.

72
Q

Lithosphere, biota, hydrosphere, and atmosphere as carbon sinks

A

-One of the largest carbon sinks is the Earth’s crust or lithosphere, where carbon is found as sedimentary rock and fossil fuels.

-Other carbon sinks include the biota (living organisms), the hydrosphere (aquatic environments), and the atmosphere (as carbon dioxide).

-Much of the carbon on Earth is in flux, meaning that it is in movement from one sink to another.

73
Q

What is a flux?

A

The process that moves an element from one reservoir or sink to another.

74
Q

What is the lithosphere?

A

The portion of the Earth that consists of the crust and upper mantle.

75
Q

What is the hydrosphere?

A

The portion of the Earth that consists of water including oceans, lakes, ponds and rivers.

76
Q

What is the biota?

A

The portion of the Earth that consists of the living organisms.

77
Q

What is the atmosphere?

A

The layer of gases surrounding the Earth.

78
Q

Diagram of the carbon cycle

A
79
Q

Drawing the carbon cycle for the exam

A

You are expected to be able to draw a model of the carbon cycle. Also, be able to label the fluxes and sinks.

80
Q

Diagram showing an example of the carbon flux

The annual carbon flux on Earth.

As is the case with models, they are simplified versions of rather complex processes, but they give a good idea of what happens to the carbon on our planet.

A
81
Q

How is the presence of carbon measured?

A

When measuring carbon, the unit is gigatonnes (Gt): 10 15 g.

82
Q

How will atmospheric carbon expected to increase?

A

It is clear that the atmospheric carbon is bound to keep on increasing (going beyond 820 Gt) over the years as humans continue to burn fossil fuels and cut down forests.

83
Q

What factors will alter the amount of carbon flow per year?

A

-These factors may be due to human activity such as deforestation or an increase in the burning of fossil fuels.

-They may be natural, such as in the case of volcanic activity.

-As mentioned in the previous section, carbon in the atmosphere can also change with the seasons when there is more CO 2 in the atmosphere during winter months (in the northern hemisphere) because there is less photosynthesis.

-Carbon can also change as ecosystems grow and develop into climax communities.

84
Q

Estimating carbon fluxes for the exam

A

You should be able to estimate carbon fluxes due to processes in the carbon cycle.

85
Q

For carbon, the cycling process involves:

I. A reservoir

II. An exchange pool

III. A biotic community

A

I, II and III

86
Q

Which process or flux decreases the amount of carbon dioxide in the atmosphere?

A

Photosynthesis

87
Q

Describe the correlation between atmospheric CO2 concentration and average global temperature

A

-A strong correlation has been established between the atmospheric carbon dioxide concentration and the average global temperature.

-Atmospheric carbon dioxide has been steadily increasing since the beginning of the industrial revolution in the 19th century.

-At that time, atmospheric carbon dioxide was around 300 ppm.

-It now stands at around 400 ppm.

88
Q

Graph showing historic atmospheric CO 2 concentrations

A
89
Q

CO2 fluctuation between seasons

A

-A closer look at the CO 2 fluctuations within each year shows that it varies with the seasons.

-CO 2 is a raw material for photosynthesis, and thus the level of atmospheric CO 2 decreases as there is an increase in the rate of photosynthesis in summer (from May to October in the northern hemisphere).

-During the spring, trees and other autotrophs tend to grow and increase their foliage, which is where photosynthesis takes place.

-In winter (November to April), the rate of photosynthesis is much lower due to lower temperatures and shorter days with less light; therefore an increase in atmospheric CO 2 is recorded.

90
Q

Graph showing mean CO2 concentration at Mauna Loa from 1958 to 2015.

A
91
Q

How have human activities increased the concentration of atmospheric carbon dioxide and methane

A

-Due to an increase in fossil fuel combustion and an increase in livestock farms.

-Both are strong contributors to the greenhouse effect.

92
Q

How do research stations ensure the reliability of climate change data?

A

-It is important to have accurate and reliable data.

-Several research stations have been established to measure atmospheric gases.

-One of the best-known stations with a long record is the Mauna Loa observatory in Hawaii.

93
Q

Which of the following will increase CO2 concentrations in the atmosphere?

I. Deforestation

II. Photosynthesis

III. Combustion of fossil fuels

IV. Cold temperatures and short days

V. Warm temperatures and long days

A

I, III, IV

94
Q

Methane can be oxidised in the atmosphere. State the two products of methane oxidation.

A

Carbon dioxide (CO2) and two molecules of water (H2O).

95
Q

The calcium carbonate within limestone can be decomposed when acid rain weathers the limestone. This releases back into the atmosphere.

A

Carbon dioxide

96
Q

Diagram of the carbon cycle (OSC)

A
97
Q

Estimate global carbon fluxes in the carbon cycle (check what is needed for exam)

A