4.1 - Covalent Bonding Flashcards

1
Q

covalent bond

A

electrostatic attraction between the nuclei of bonded atoms and a shared pair of electrons

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2
Q

covalent bond is formed

A

formed between atoms by the sharing of a pair of electrons

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3
Q

electrostatic attraction

A

The attraction between the shared pair of electrons and the nuclei of the atoms involved in a covalent bond

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4
Q

covalently bonded substances may be

A

simple molecular structures or giant covalent structures
- Simple molecular structures –> oxygen and water
- Giant covalent structures –> diamond and graphite

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5
Q

simple molecular structures have low melting and boiling points because

A

There are weak intermolecular forces between the molecules
These forces require little energy to overcome

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6
Q

C60 is a simple molecular structure that

A

can not conduct electricity

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7
Q

as the relative molecular mass of a substance increases

A

the melting and boiling point will increase as well
-> more electrons in the structure, so there are more intermolecular forces of attraction that need to be overcome
-> larger amounts of heat energy are needed to overcome these forces, causing the compound to have a higher melting and boiling point

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8
Q

simple molecular structures are poor conductors of electricity (even when molten) because

A
  • no free ions or electrons to move and carry the charge -> neutral charge
  • most covalent compounds do not conduct at all in the solid state
  • insulators
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9
Q

giant covalent structures

A

solids with high melting points, giant lattices

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10
Q

examples of giant covalent structures

A

diamond and graphite

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11
Q

all giant covalent structures have high melting points because

A
  • strong covalent bonds between atoms
  • these require lots of energy to overcome
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12
Q

properties of diamond and use

A

diamond is very hard:
- each carbon atom is covalently bonded to four other carbon atoms
- the covalent bonds are very strong
- tetrahedron shape (each atom bonded to four carbon atoms)
the hardness of diamond makes it useful for cutting tools

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13
Q

Diamond has a high melting point because

A

a giant covalent structure
- there are strong covalent bonds between atoms which need lots of energy to break

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14
Q

properties of graphite and use

A
  • soft and slippery
  • each carbon atom is bonded to three other carbon atom forming layers
  • layers are free to slide over each other because there are only weak forces between the layers, not covalent bonds
  • graphite is used as pencil lead
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15
Q

graphite can conduct electricity and heat because

A

delocalised electrons are free to move

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16
Q

graphite has a high melting point because

A
  • giant covalent structure
  • strong covalent bonds between atoms which need lots of energy to break
17
Q

covalent compounds do not usually

A

conduct electricity

18
Q

molecule

A

group of atoms joined by covalent bonds

19
Q

why does lithium fluoride form ionic bonds

A

lithium gives one electron to fluoride (metal -> non-metal)
- flouride gains one electron and hydrogen looses one

20
Q

relative mass

A

(number x percent)+(number x percent) / 100

21
Q

metals structure and bonding

A

giant metallic
metallic
-> high MP+BP

22
Q

metals with non-metal structure and bonding

A

giant ionic
ionic
-> high MP+BP

23
Q

group 4 structure and bonding

A

giant covalent
covalent bonds
-> high MP+BP

24
Q

non-metals structure and bonding

A

simple molecular
covalent bonds
-> low MP+BP

25
Q

C60 properties

A
  • simple molecular structure
  • allotrope of carbon
  • 60 carbon atoms
26
Q

C60 properties mentioning structure

A
  • low MP/BP point -> forces between molecules are weak but has large molecules
  • so C60 has high MP for a molecular substance
  • molecules are neutrals -> not able to conduct electricity -> insulator
  • soft and slipper -> weak forces allow molecules to slide over each other -> malleable
27
Q

silicon dioxide has high melting point

A
  • giant structure -> lots of strong covalent bonds
  • takes a huge amount of energy to break
28
Q

silicon dioxide does not conduct electricity

A
  • electrons not free to move
  • stuck in covalent bonds
29
Q

giant ionic has high melting point because

A
  • strong forces between oppositely charged ions -> strong and takes lots of energy to break
30
Q

giant ionic conducts electricity when

A

molten -> ions free to move and carry charge
solid - fixed position and doesn’t carry charge

31
Q

giant metallic has high melting point

A

strong electrostatic attraction between positive metal ions and delocalised electrons

32
Q

giant metallic conducts electricity

A

delocalised electrons free to move

33
Q

since giant metallic is metallic the ions

A

are in layers and can easily slide over each other