4.1 - Covalent Bonding Flashcards
covalent bond
electrostatic attraction between the nuclei of bonded atoms and a shared pair of electrons
covalent bond is formed
formed between atoms by the sharing of a pair of electrons
electrostatic attraction
The attraction between the shared pair of electrons and the nuclei of the atoms involved in a covalent bond
covalently bonded substances may be
simple molecular structures or giant covalent structures
- Simple molecular structures –> oxygen and water
- Giant covalent structures –> diamond and graphite
simple molecular structures have low melting and boiling points because
There are weak intermolecular forces between the molecules
These forces require little energy to overcome
C60 is a simple molecular structure that
can not conduct electricity
as the relative molecular mass of a substance increases
the melting and boiling point will increase as well
-> more electrons in the structure, so there are more intermolecular forces of attraction that need to be overcome
-> larger amounts of heat energy are needed to overcome these forces, causing the compound to have a higher melting and boiling point
simple molecular structures are poor conductors of electricity (even when molten) because
- no free ions or electrons to move and carry the charge -> neutral charge
- most covalent compounds do not conduct at all in the solid state
- insulators
giant covalent structures
solids with high melting points, giant lattices
examples of giant covalent structures
diamond and graphite
all giant covalent structures have high melting points because
- strong covalent bonds between atoms
- these require lots of energy to overcome
properties of diamond and use
diamond is very hard:
- each carbon atom is covalently bonded to four other carbon atoms
- the covalent bonds are very strong
- tetrahedron shape (each atom bonded to four carbon atoms)
the hardness of diamond makes it useful for cutting tools
Diamond has a high melting point because
a giant covalent structure
- there are strong covalent bonds between atoms which need lots of energy to break
properties of graphite and use
- soft and slippery
- each carbon atom is bonded to three other carbon atom forming layers
- layers are free to slide over each other because there are only weak forces between the layers, not covalent bonds
- graphite is used as pencil lead
graphite can conduct electricity and heat because
delocalised electrons are free to move