4. Chemistry Flashcards
Provides a classification and labeling of hazardous chemical
GHS: Globally Harmonized System
pH (definition and scale)
Potential of Hydrogen, which is a logarithmic scale which measures H ion activity
0-6: acidic
7: neutral
8-14: alkaline
¿When a solution is considered highly corrosive?
pH less than 2 (highly acidic) or greater than 12.5 (highly basic)
Formula of pH & pOH
Acidic: pH = -log (H+)
H+: concentration of hydrogen ion (M)
(H+) = 10^(-pH)
Alkaline: pH = 14 - pOH
pOH = -log (OH-)
OH-: concentration of hydroxide ion (M)
Flash points of flammable and combustible liquids
CL > 100 ºF and < 200 ºF
FL <100 ºF
Formula of PPM regarding %LEL (lower explosive limit)
PPM = %LEL x 10,000
e.g.: for 1.4% LEL -> 1.4 * 10,000 = 14,000 ppm
ACGIH
American Conference of Governmental Industrial Hygienists
Percent concentration to PPM
PPM = % * 10,000
PPM to concentration in mg/m3
Conc. mg/m3 = (molecular weight of substance g/mol)x(PPM) / 24.45
Detectors: PID ; FID
PID: Photo Ionization Detector
FID: Flame Ionization Detector
TWA:definition and formula
Time Weighted Average: average exposure over an eight-hour day (in a 40-hour work week).
TWA = (C1T1 + C2T2 + … + Cn*Tn) / (T1 + T2 + … + Tn)
C: concentrations of the chemical
T: lengths of time over which concentrations are measured (sum 8 hours?)
Formula to exposure to chemical mixtures
E = C1/TLV1 + C2/TLV2 + … + Cn/TLVn
- C: concentrations of each chemical
- TLV: threshold limit value for each chemical
; a measurement of a chemical determinant in the biological media of those exposed and is an indicator of the uptake of a substance.
Biological Exposure Index (BEI)