3.3 Halogenoalkanes Flashcards
Are halogenoalkanes soluble in water
Insoluble as C-H non polar, not compensated enough by C-X bond polarity
Do halogenoalkanes have a polar bond
Yes as halogen has high electronegativity than C
Which IMF do halogenoalkanes have
Permanent dipole-dipole and van der waals
What is a nucleophile
A negatively charged ion/electronegative atom with lone pair of electrons which can be donated to an electron deficient atom
3 Examples of nucleophiles
:OH-
:CN-
:NH3
What is nucleophilic substitution
A reaction where a nucleophile donates a lone pair of electrons to electropositive C atom, electronegative atom leaves (replaced by nucleophile)
Draw the mechanism for the reaction of bromoethane with NaOH
Draw the mechanism for the reaction of bromoethane with KCN
Draw the mechanism for the reaction of bromoethane with NH3
Draw the mechanism for the reaction of bromoethane with NaOH in ethanol
What are the conditions/reactants needed for the elimination reaction of haloalkanes
NaOH or KOH dissolved in ethanol (no water)
Heated
What is formed in the elimination reaction of haloalkanes
An alkene, water and halogen ion