3.1.7 Oxidation, Reduction, and Redox Reactions Knowledge Flashcards

1
Q

what is oxidation in terms of transfer of electrons?

A

the loss of electrons

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2
Q

what happens to the oxidation state, when a species is oxidised?

A

increases - number becomes more positive

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3
Q

what is reduction in terms of transfer of electrons?

A

the gain of electrons

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4
Q

what happens to the oxidation state, when a species is reduced?

A

decreases - number becomes more negative

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5
Q

what is a redox reaction?

A

reaction where oxidation and reduction take place at the same time

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6
Q

what is a reducing agent in terms of transfer of electrons?

A
  • electron donor
  • a reducing agent is itself oxidised
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7
Q

what is an oxidising agent in terms of transfer of electrons?

A
  • electron acceptor
  • an oxidising agent is itself reduced
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8
Q

what are oxidation states used for?

A

to follow the movement of electrons in redox reactions; to identify which substances have been oxidised and reduced

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9
Q

is the charge or number given first in oxidation states?

A

charge

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10
Q

what oxidation state do uncombined elements have?

A

0

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11
Q

what is the sum of all oxidation states in a compound?

A

0

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12
Q

what is the oxidation state of a simple ion equal to?

A

its charge

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13
Q

what is the sum of all oxidation states in a complex ion equal to?

A

its charge

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14
Q

what is the oxidation state(s) of hydrogen?

A
  • usually +1
  • in metal hydrides (e.g. LiH) -1
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15
Q

what is the oxidation state(s) of group 1 metals?

A

+1

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16
Q

what is the oxidation state(s) of group 2 metals?

A

+2

17
Q

what is the oxidation state(s) of aluminium?

A

+3

18
Q

what is the oxidation state(s) of oxygen?

A
  • usually -2
  • in peroxides (e.g. Na2O2), -1
  • when reacted with fluorine (OF2), +2
19
Q

what is the oxidation state(s) of fluorine?

A

-1

20
Q

what is the oxidation state(s) of chlorine?

A
  • usually -1
  • is positive if reacted with oxygen or fluorine
21
Q

what is the oxidation state(s) of bromine?

A
  • usually -1
  • is positive if reacted with oxygen or fluorine
22
Q

what is the oxidation state(s) of iodine?

A
  • usually -1
  • is positive if reacted with oxygen or fluorine
23
Q

why is the oxidation state of fluorine always -1?

A

it is the most electronegative element; no other element can remove an electron from fluorine

24
Q

in what order are oxidation states assigned?

A
  • Uncombined elements (0)
  • Metals (G1, G2, Al)
  • Fluorine (-1)
  • Hydrogen (+1)
  • Oxygen (-2)
  • Chlorine (-1)
25
Q

how do you balance a simple half-equation?

A

with e-

26
Q

what are the rules for balancing complicated half-equations?

A
  1. balance the main atom (not H or O)
  2. Balance O using H2O
  3. Balance H using H+
  4. Balance charge using e-
27
Q

what are the steps for combining half-equations?

A
  1. multiply one or both half-equations until they both contain the same no. electrons
  2. add the reactants from both half-equations together
  3. add the products from both half-equations together
  4. cancel out the electrons
28
Q

what is a disproportionation reaction?

A

a reaction in which one type of atom is both oxidised and reduced

29
Q

what is oxidation in terms of oxygen transfer?

A

gain of oxygen

30
Q

what is reduction in terms of oxygen transfer?

A

loss of oxygen

31
Q

what is an oxidising agent in terms of oxygen transfer?

A

substance which gives oxygen to another substance

32
Q

what is an reducing agent in terms of oxygen transfer?

A

substance which removes oxygen from another substance.

33
Q

what is oxidation in terms of hydrogen transfer?

A

loss of hydrogen

34
Q

what is reduction in terms of hydrogen transfer?

A

gain of hydrogen

35
Q

what is an oxidising agent in terms of hydrogen transfer?

A

oxidising agents remove hydrogen from another substance

36
Q

what is an reducing agent in terms of hydrogen transfer?

A

reducing agents give hydrogen to another substance

37
Q
A