3.1.3lipids and phospholipids Flashcards
What are fatty acids?
Long non-polar hydrocarbon chains containing a COOH (carboxylic group) at one end.
What are the roles of lipids
- Source of energy: twice as much as carbohydrates for same mass
- Waterproofing: insoluble in water
- Insulation: slow heat conductors so help retain heat
- Protection: fat stored around delicate organs
- Phospholipids make up cell membranes
How are triglycerides formed?
Condensation reactions between 1 glycerol and 3 fatty acids to produce 3 molecules of water.
Forms ester bond.
Describe the structure and formation of triglycerides
3 fatty acids combined with one glycerol molecule
Glycerol is a fatty acid containing 3 hydroxyl groups which react with 3 fatty acids to form ester bonds
Are phospholipids hydrophilic or hydrophobic?
Hydrophilic head, hydrophobic tail
What are saturated fatty acids?
- Fatty acids with no double bonds between 2 carbon atoms
- saturated with hydrogen
What are phospholipids?
2 fatty acids, one glycerol and one phosphate molecule. (Like triglycerides but one fatty acid replaced by phosphate molecule)
Are lipids soluble?
Soluble in organic solvents (e.g. alcohol)
Insoluble in water
Are triglycerides hydrophilic or hydrophobic?
Hydrophobic
What are the differences between triglycerides and phospholipids?
- Triglycerides have 3 fatty acids but phospholipids have 2 fatty acids and a phosphate group
- Triglycerides are hydrophobic but phospholipids have hydrophobic and hydrophilic regions
- Phospholipids form bilayer in water but Triglycerides don’t
What are the similarities between triglycerides and phospholipids?
- Contain ester bonds
- Contain glycerol
- Fatty acids may be saturated or unsaturated
- Insoluble in water
- Contain C, O and H
What are unsaturated fatty acids?
Mono-unsaturated fatty acids: one carbon to carbon double bond
Poly-unsaturated fatty acids: 2+ carbon to carbon double bonds
Double bonds cause the chain to bend
What is the general structure of a fatty acid?
R.COOH
R group is a long hydrocarbon chain
Compare the structure of starch and cellulose MOVE
- Both polysaccharides/polymers of glucose
- Both glycosidic bonds
- Both contain O H C
- Starch helical/coiled, cellulose straight
- starch branched, cellulose unbranched
- starch no microfibrils, cellulose microfibrils
- starch 2 types of molecule (amylose and amylopectin)
- starch 1-6 glycosidic bonds, cellulose 1-4