3 Reversible reactions and equilibria Flashcards

1
Q

What are two reversible reactions?

A
  • Dehydration of copper sulfate crystals.
  • Heating ammonium chloride.
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2
Q

What is the dehydration of copper sulfate crystals?

A

If you heat blue copper (II) sulfate crystals gently, the blue crystals turn to a white powder and water is driven off.

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3
Q

How is the water driven off?

A

Heating causes the crystals to lose their water of crystallisation and white anhydrous copper (II) sulfate is formed.

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4
Q

What does anhydrous mean?

A

Without water.

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5
Q

What is the equation for the dehydration of copper sulfate crystals?

A

CuSO4.5H2O —> CuSO4 + 5H2O
Blue White

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6
Q

What is needed for this reaction to occur?

A

Heat.

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7
Q

What happens if you add water to the white solid?

A

It turns blue again; it also becomes very warm.

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8
Q

What is the equation for the rehydration of copper sulfate crystals?

A

CuSO4 + 5H2O —> CuSO4.5H2O
White Blue

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9
Q

What happens in the during of this reaction?

A

Heat is released from this reaction.

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10
Q

What has happened with the dehydration and rehydration of the copper sulfate crystals?

A

The original change has been exactly reversed. Even the heat that you put in has been given out again. This is called a reversible reaction.

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11
Q

What is a reversible reaction?

A

A reversible reaction is one that can go both ways, in other words, reactants react to form products and products can react to form reactants.

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12
Q

How can we indicate that a reaction is reversible?

A

With a special arrow.

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13
Q

What does this arrow look like?

A

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14
Q

What is heating ammonium chloride?

A

If you heat ammonium chloride, the white crystals disappear from the bottom of the tube and reappear further up.

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15
Q

What does heating ammonium chloride do?

A

Heating ammonium chloride splits it into the colourless gases ammonium and hydrogen chloride.

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16
Q

What is the equation when heating ammonium chloride?

A

NH4CI —> NH3 + HCI
white solid —> colourless gases

17
Q

What is needed for this reaction to occur?

A

Heat.

18
Q

How is this reaction reversed?

A

Those gases recombine further up the tube, where it is cooler, to form a white solid.

19
Q

What is the equation used when cooling down ammonium chloride?

A

NH3 + HCI —> NH4CI
colourless gases —> white solid

20
Q

What is released from this reaction?

A

Heat.

21
Q

When does this reaction reverse?

A

When the conditions are changed from hot to cool.

22
Q

What kind of reaction is this an example of?

A

Thermal decomposition between an acid and a base.

23
Q

How can this reaction be represented as being reversible?

A

NH3 + HCI ⇌ NH4CI