28.3 Organic synthesis routes (aliphatic) Flashcards

1
Q

haloalkane to alcohol

A

NaOH aqueous
heat and reflux

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2
Q

alcohol to haloalkane

A

sodium halide
H2SO4

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3
Q

primary alcohol to aldehyde

A

K2Cr2O7/H2SO4
heat and distillation

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4
Q

primary alcohol to carboxylic acid

A

K2Cr2O7/H2SO4
heat and reflux

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5
Q

secondary alcohol to ketone

A

K2Cr2O7/H2SO4
heat and reflux

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6
Q

aldehyde to primary alcohol

A

NaBH4/H2O

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7
Q

aldehyde to hydroxynitrile

A

HCN
H2SO4/NaCN

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8
Q

aldehyde to carboxylic acid

A

K2Cr2O7/H2SO4
heat and reflux

no H2O produced

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9
Q

alkene to alkane

A

H2/Ni catalyst

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10
Q

alkane to haloalkane

A

X2/UV light

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11
Q

primary alcohol to alkene

A

H3PO4
heat

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12
Q

alkene to primary alcohol

A

H3PO4
steam

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13
Q

carboxylic acid to ester

A

alcohol/H2SO4
heat and reflux

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14
Q

ester to carboxylic acid

A

dilute aqueous acid
heat and reflux

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15
Q

ester to carboxylate salt

A

NaOH and H2O
heat and reflux

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16
Q

carboxylic acid to acyl chloride

A

SOCl2

17
Q

acyl chloride to carboxylic acid

A

H2O

18
Q

acyl chloride to primary amide

A

2x NH3

19
Q

acyl chloride to secondary amide

A

2x primary amide

20
Q

haloalkane to nitrile

A

NaCN in ethanol

21
Q

haloalkane to amine

A

NH3/ethanol

22
Q

nitrile to amine

A

H2/Ni catalyst

23
Q

nitrile to carboxylic acid

A

H20/HCl
heat

24
Q

nitrate to amine

A

Sn and HCl
6 [H]

25
Q

carboxylic acid to carboxylate salt

A

NaOH