2.7 - Polymers Flashcards
Man-made polymers are referred to as ________.
plastics
What are plastics derived from?
- Coal, gas, cellulose and commonly crude oil.
- Crude oil needs to be processed before use.
What is fractional distillation?
- The process of fractional distillation separates crude oil into useful hydrocarbon products.
- The different components that are separated out are known as fractions.
- The fractions include petrol, naptha, kerosene, diesel and bitumen.
In the process of producing plastics, what happens after fractional distillation?
- A chemical called naphtha, a mix of hydrocarbons used for the production of many different plastic polymers, is vented off from the distillery column.
- This then undergoes a process called cracking so that individual hydrocarbons, called monomers, are produced.
In the process of producing plastics, what happens after the hydrocarbon is cracked?
- Monomers undergo polymerisation, which links monomers together to make a polymer chain.
- For example, a long chain of ethylene forms polyethylene which is used to make carrier bags, toys and bottles.
Give an example of a common bioplastic.
- The one of the most common plant-based polymers is polylactic acid (PLA).
- It is commonly used in a 3D printer.
- PLA is obtained from corn starch - the corn is fermented to produce lactic acid, which is polymerised to produce polylactic acid.
Why is the development and use of bioplastics important?
Bioplastics are being continually developed to combat the environmental concerns related to the non-biodegradable properties of plastic polymers.
What are the properties of thermoforming plastics?
- These are easy to mould and shape when hot.
- They can be formed into complex shapes and reformed multiple times.
- They are lightweight, strong, waterproof and corrosion resistant.
What are the properties of thermosetting plastics?
- A thermoset is irreversibly hardened and cannot be reformed.
- It makes a hard, but often brittle plastic which resists deformation.
- It has good heat and electrical resistance (good insulator) and is commonly used for electrical components, domestic plugs and switches.
- It also has good chemical resistance and structural integrity. It can be reinforced to produce a strong, durable material.
What are some ways of modifying plastics?
- Stabilisers
- Pigments
- Plasticisers
How do stabilisers modify plastics?
- Stabilisers can be added to make plastic more resistant to heat and light.
- Over time UV light degrades plastic, turning it brittle and faded.
- This has an impact on strength, and changes the surface appearance and texture.
How do pigments modify plastics?
Pigments can be added to vary the colour of plastics.
How do plasticisers modify plastics
- Plasticisers give a material improved flexibility .
- Are commonly used in PVC to improve applications such as sheathing for electrical cables and car interior trim.
What are some different stock forms that plastics are produced in?
- Film
- Granules / pellets
- Foam
- Rods / tubes
- Powder
- Sheet
What is film used for? (Stock form)
Used for packaging, bags, labels and sheeting.
What are granules / pellets used for? (Stock form)
Used for extrusion and injection moulding.
What is foam used for? (Stock form)
- Can be made flexible or rigid.
- Used for thermal insulation and packaging.
What are rods / tubes used for? (Stock form)
- Used in electrical, plumbing, garden, military and medical applications.
- Can be bent to shape.
What is powder used for? (Stock form)
- Mixes well with additives and dyes.
- Also used in resin glues, spray coating and 3D printing.