2.3 Carbohydrates and lipids Flashcards

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1
Q

Define polymer

A

A material or substance that is made of large molecules composed of multiple, repeating sub-units

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2
Q

3 examples of hexose mono-saccharides

A

Galactose, glucose, fructose

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3
Q

Monosaccharides–> Disaccharides: What type of reaction and which bond is formed?

A

Condensation reaction and a glycosidic bond is formed.

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4
Q

What is needed to make the condensation reactions occur?

A

A catalyst

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5
Q

Maltose, sucrose, lactose: Animals or plants?

A

Maltose: Animal
Lactose: Animal
Sucrose: Plant

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6
Q

What is maltose made of and where is it found?

A

Made of glucose + glucose and commonly found in starchy grains

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7
Q

What is lactose made of and where is it found?

A

Glucose + Galactose. Commonly found in milk

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8
Q

What is sucrose made of and where is it found?

A

Glucose + Fructose. Commonly found in sugar canes and sugar beets

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9
Q

What are the 4 common polysaccharides?

A

Cellulose, starch (amylose), starch (amylopectin), glycogen

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10
Q

Orientation and bonding of cellulose

A

1-4 bonds between alternately oriented Beta-D glucose molecules

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11
Q

Orientation and bonding of amylose

A

1-4 glycosidic bonds between Alpha-D glucose

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12
Q

Orientation and bonding of amylopectin

A

1-6 links in the branches but mostly 1-4 links

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13
Q

Orientation and bonding of glycogen

A

Consists of 1-4 and 1-6 bonds between Alpha-D glucose

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14
Q

What does a 1-4 bond mean?

A

A bond between first and fourth carbon

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15
Q

Is the chain straight or bent for 4 polysaccharides?

A

Cellulose- Straight
Amylose- Bent and helical
Amylopectin- Bent and globular
Glycogen- Bent

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16
Q

Is the chain branched or unbranched for the 4 polysaccharides?

A

Unbranched: Cellulose and amylose
Branched: Amylopectin and glycogen

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17
Q

Properties of cellulose

A

Insoluble, high tensile strength, low conductivity

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18
Q

Properties of starch

A

Insoluble, doesn’t affect osmotic balance, molecules vary in size, easy to remove and add glucose units

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19
Q

Properties of glycogen

A

More extensively branched and compact than amlyopectin

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20
Q

Function of cellulose

A

Structural component of plant cell walls

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21
Q

Function of starch

A

Useful for glucose and energy storage. It is a temporary store in plant cells when glucose is being made faster than it’s being exported

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22
Q

Function of glycogen

A

Form of medium term energy storage in animals

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23
Q

How is amylopectin useful?

A

It gives starch its characteristic stickiness. Useful in food, paper, chemical industries as glue and lubricant.

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24
Q

Difference between glucose and fructose

A

Glucose and fructose both have 6 carbons however glucose has a hexagonal ring with 5 carbons and the 6th connected to the 5th. Fructose has a pentagonal ring with 4 carbons and the one connected to the first and fourth carbon each.

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25
Q

What is the structure of sucrose?

A

It is made of fructose and glucose so they are connected by an oxygen atom at the first carbon of glucose and the fourth carbon of fructose

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26
Q

Similarities and differences between glycogen, amylose and amylopectin

A

All 3 are curved and consist of alpha-glucose. Amylose is unbranched. Amylopectin is branched but after around every 20 subunits while glycogen is branched but after around every 10 subunits

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27
Q

Generalized structure of a fatty acid

A

CH3(CH2)xCOOH

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28
Q

What is a saturated fatty acid?

A

It is a fatty acid that has no double bonds between any of the carbon atoms

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29
Q

Monounsaturated

A

Only one double bond in the carbons

30
Q

What do you call a fatty acid with multiple double bonds in the carbons?

A

Polyunsaturated

31
Q

What are the types of unsaturated fatty acids?

A

Cis-isomers and trans-isomers

32
Q

Cis/trans-isomers: Natural or synthesized?

A

Cis: Very common in nature
Trans: Rare in nature, usually artificially produced

33
Q

How are trans-isomers artificially produced to produce solid fats like margarine from veg. oils?

A

They are hydrogenated: Hydrogen is added under pressure to increase spreadability and increase shelf life

34
Q

Cis/trans-isomers: Positioning of hydrogen atoms

A

Cis: All on the same side of the carbon atoms
Trans: Position will alternate on every carbon

35
Q

Cis/trans-isomers: Shape of fatty acid chain

A

Cis: Double bond causes a bend in the chain
Trans: There will be no bend

36
Q

Cis/trans-isomers: Packing of fatty acids

A

Cis: Loosely packed due to bend
Trans: Can be closely packed

37
Q

Cis/trans-isomers: Liquid or solid at RTP

A

Cis have low MP so liquid at RTP while trans have high MP so solid at RTP

38
Q

Causes of CHD

A
  • Caused by buildup of fatty deposits around artery walls so blood flow is restricted
  • High levels of LDL means more deposits
  • Factors can include smoking, high cholesterol/BP, sedentary lifestyle
39
Q

Possible effects of CHD

A
  • Reduction of blood flow = chest pain, shortness of breath, blood clots or a heart attack
40
Q

Why is cellulose indigestible for most animals?

A

It is made of beta-glucose and most animals lack the enzyme to break it down

41
Q

Why is amylose preferred storage in plants?

A

They take up less space

42
Q

What do triglycerides consist of?

A

One glycerol molecule and 3 fatty acids

43
Q

What does a glycerol molecule look like?

A

It has 3 carbons. Each carbon has a hydrogen and OH group while the carbon ends also have an extra hydrogen

44
Q

What are the bonds between the fatty acid and the glycerol molecule?

A

Ester bonds

45
Q

How are ester bonds formed?

A

Through condensation between the OH groups of glycerol and fatty acids to produce water and an ester bond.

46
Q

How are phospholipids different from triglycerides?

A

They also have a glycerol molecule but they only have 2 fatty acids and a chain with a phosphate group instead.

47
Q

Why are steroids considered lipids?

A

Because they are hydrophobic and insoluble even though they have a four-ring structure

48
Q

Word equation for formation of triglycerides

A

Glycerol + 3 fatty acids –> Triglyceride + 3H2O

49
Q

Lipids and carbs: Short or long term energy storage

A

Lipids: Long term
Carbs: Short term

50
Q

The chemical energy in glucose is for immediate use in which process?

A

Respiration

51
Q

Where is glycogen stored?

A

In the liver and muscles

52
Q

Why is glycogen used in preference to lipids?

A

Short term as it can be broken down easily. It can be used in aerobic and anaerobic conditions unlike fats which require aerobic only

53
Q

Where and how are lipids stored in animals?

A

Stored in specialized groups of cells called “Adipose tissues”. They are usually located beneath the skin or around organs like kidneys

54
Q

How are lipids better than carbs in terms of storage?

A
  • The amount of energy released per gram is double in lipids so it’s more efficient.
  • They are also much lighter
  • Fats are stored as droplets while 1g of carbs is associated with 2g of water
55
Q

Advantages of lipids

A
  • Non polar so they will dissolve other non-polars without affecting movement of water
  • Water-insoluble so they provide waterproof layers
  • They provide excellent insulation
  • Fat is liquid at body temp. so it can act as a shock absorber hence its position around organs.
56
Q

What does BMI stand for?

A

Body Mass Index

57
Q

How is BMI calculated?

A

Mass(kg)/ Height(m)^2

58
Q

How would relationship of height and BMI change with fixed body mass?

A

If height increases, BMI will decrease and vice-versa. Negative correlation

59
Q

How can one reduce body mass?

A
  • Exercise more
  • Reduce amount of fats in their diet (lipid intake)
  • Drink more water and cut down on sugar
60
Q

How does one use a nomogram?

A

Draw a line from person’s height to body mass and where it crosses scale in between is respective BMI

61
Q

How is the lightness of lipids an advantage for birds?

A

It is important for animals that fly like birds and bats as it helps when they migrate or fly long distances and hence require long-term energy storage that’s also light.

62
Q

How do the different fats influence HDL and LDL levels in the blood?

A
  • Saturated increase LDL levels (bad)
  • Trans fats increase LDL AND decrease HDL (bad)
  • Cis fats increase HDL levels (good)
63
Q

What are HDLs and LDLs

A

High density and low density lipoproteins

64
Q

What do LDLs do?

A

They carry cholesterol from liver to the rest of the body

65
Q

What do HDLs do?

A

They gather excess cholesterol and carry it back to the liver for disposal

66
Q

Do LDLs raise or lower cholesterol levels?

A

LDLs increase while HDLs decrease

67
Q

2 main lipid health claims

A
  • Diets rich in saturated fats and trans fats increase the risk of CHD
  • Diets rich in monounsaturated and polyunsaturated (cis) fats decrease the risk of CHD
68
Q

How has evidence for lipid health claims been collected?

A
  1. Epidemiological studies comparing different population groups
  2. Intervention studies that monitor cohorts following dietary modifications
  3. Experimental designs utilising animal models or data based on autopsies
69
Q

What is the counter argument for correlation between saturated fats and CHD?

A

Certain populations do not fit this trend (e.g. the Maasai tribe in Africa have a fat-rich diet but very low rates of CHD)

70
Q

Counter argument for: people who have died from CHD have been found to have high conc. of trans-fats in the fatty deposits

A

Genetic factors may play a role (e.g. blood cholesterol levels only show a weak association to dietary levels)