18.1 - Rates of reactions 2 Flashcards
How can you calculate rate of reaction using concentration?
Rate = change in concentration / time
What is the rate of reaction proportional to?
The concentration of a particular reactant raised to a power.
The power is the order of reaction for that reactant.
What is a zero order reactant?
The concentration of that reactant has no effect on the rate.
What is a first order reactant?
The rate depends on the concentration of the reactant raised to the power of 1.
e.g. doubling the concentration (x2) doubles the rate (x2)
What is a second order reactant?
The rate depends on the concentration of the reactant raised t the power of two.
e.g. doubling the concentration (x2) increases the rate by a factor of 4 (x4) because 2² = 4
What is the rate equation?
The rate equation gives the mathematical relationship between the concentrations of the reactants and the reaction rate.
What is the rate constant?
The rate constant k is the proportionality constant. It is the number that mathematically converts between the rate of reaction and concentration and orders.
What is the overall order of a reaction?
The overall order of a reaction gives the overall effect of the concentrations of all reactants on the rate of reaction.
Overall order = sum of all orders with respect to each reactant