15.1.3 Converting Between Kc and Kp Flashcards

1
Q

In the ideal gas equation, the volume, V, ____________________

A

varies inversely with pressure.

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2
Q

True or false?

The term Δn, in the equation relating Kp and Kc, the value for Kp = Kc (RT)Δn, cannot be zero.

A

false

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3
Q

Ammonia is synthesized in the following reaction:

N2(g) + 3H2(g) —> 2NH3(g)

The Kc and Kp values were 0.105 and 0.000028, respectively. At what temperature did this reaction take place? (The value of R is 0.0821 Latm/molK)

A

745 K

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4
Q

For the following reaction:

4NH3(g) + 3O2(g) —> 2N2(g) + 6H2O(g)

What is the value of delta (triangle) n?

A

1

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5
Q

For the following reaction, the equilibrium constant Kp is 0.0005 at 300 degrees C. What is the value of Kc? (The value of R is 0.0821 Latm/molK)

2SO3(g) —> 2SO2(g) + O2(g)

A

0.0000106

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6
Q

For the following reaction in which ammonia is synthesized, the equilibrium constant, Kc, is 0.65 at 375 degrees C.

N2(g) + 3H2(g) —> 2NH3(g)

Initial concentration of H2, N2, and NH3 are 0.76M, 0.60M, and 0.48M, respectively. In which direction will the reaction proceed to reach equilibrium?

A

right to left

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7
Q

The Haber process involves the synthesis of ammonia from nitrogen and hydrogen.

N2(g) + 3H2(g) 2NH3(g)

For this reaction, the equilibrium, constant Kp = 0.00043 at 397 degrees C. What is the value of Kc? (R = 0.0821 Latm/molK)

A

1.3

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8
Q

In a reaction, gaseous reactants react to give gaseous products. How is the concentration of the reactants and products related to their pressures?

A

directly

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9
Q

When two grams of calcium carbonate are heated in a closed 4 L vessel, the following equilibrium is achieved:

CaCO3(s) CaO(s) +CO2(g)

At 800 degrees C, the partial pressure of CO2 is 0.236 atmospheres. What is the value of Kc? (R = 0.0821 Latm/molK)

A

2.68 x 10^-3

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10
Q

At 20 degrees C, the vapor pressure of water is 0.0231 atm. What are the values of Kp and Kc for this process?

H2O(l) H2O(g)

A

Kp = 0.0231 and Kc = 9.6 x 10^-4

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