1.2 Bonding Flashcards
Ammonium
NH4 +
Hydroxide
OH-
Nitrate
NO3 -
Nitrite
NO2 -
Hydrogencarbonate
HCO3 -
Chlorate (I)
ClO-
Chlorate (V)
ClO3 -
Carbonate
CO3 2-
Sulfate
SO4 2-
Sulfite
SO3 2-
Dichromate
Cr2O7 2-
Sulfide
S2-
Phosphate
PO4 3-
Nitride
N3-
Linear
180°
Trigonal planar
120°
Tetrahedral
109.5°
Tetrahedral
109.5°
Trigonal bipyramidal
120°
90°
Octahedral
90°
V-shape
2 bonding
1 lone
117.5°
Pyramidal
3 bonding
1 lone
107°
See-saw
4 bonding
1 lone
119
89
Square pyramidal
5 bonding
1 lone
89
V-shape
2 bonding
2 lone
104.5
T-shape
3 bonding
2 lone
89
Square Planar
4 bonding
2 lone
90
Describe the structure and particles of metallic bonding
Structure: giant metallic lattice
Particles: positive metal ions
delocalised electrons
Describe the structure and particles within ionic bonding
Structure: giant ionic lattice
Particles: negative and positive ions
Describe the structure and particles of macromolecular covalent bonding
Structure: macromolecular
Particles: atoms
Describe the structure and particles of simple molecular covalent bonding
Structure: simple molecular
Particles: molecules
Metallic bonding definition
The strong electrostatic forces of attraction between positive metal ions and a sea of delocalised electrons
Properties of metals
Conductivity: good electrical and thermal conductors
Strength: very strong
Malleable: highly malleable
Melting point: stronger the metallic bonds, the higher the melting or boiling point
Why are metals good conductors?
The electrical current can be transferred through the delocalised electrons
Why are most metals strong?
There is strong electrostatic forces of attraction between the metal ions and delocalised electrons
Why are metals malleable?
The layers of metal ions can slide over each other
What are the two types of covalent bonds?
Macromolecular
SImple molecular
Covalent bond definition
A shared pair of electrons between two atoms
Examples of macromolecular structures
Carbon
Silicon
Silicon oxide
Ionic bonding definition
The strong electrostatic attraction between two oppositely charged ions
How do you know what forms the positive or negative ion?
Electrons are transferred from the metal to the non metal
The metal will therefore always form the positive ion and the non metal will be negative
Properties of ionic compounds
High melting point and boiling point
Electrical conductivity
Brittle
Coordinate bond definition
A shared electron pair which both have come from there same atom
How do you represent a covalent bond?
An arrow
Electronegativity definition
The power of an atom to attract the pair of electrons in a covalent bond
How does electronegativity change across the periodic table
Increases
How does electronegativity change as you go down the periodic table
Decreases
Why does the electronegativity change as you go across the periodic table?
The number of protons increases
Shielding stays the same
The ability to attract electrons in a covalent bond increases
What are the types of intermolecular forces?
Induced dipole dipole
Permanent dipole dipole
Hydrogen bonding
What type of IMF does a molecule have if it is polar?
Permanent dipole dipole
What type of IMF does a molecule have if it isn’t polar?
Induced dipole dipole
What does polar mean?
What type of IMF is the strongest?
Hydrogen
When does hydrogen bonding occur?
Between a H bonded to an O, N or F
How does hydrogen bonding arise?
Large difference in electronegativity between the oxygen and hydrogen
This creates a dipole on the O-H
The lone pair on the oxygen atom in one molecule strongly attracts the partially positive hydrogen atom in another molecule
When does PDD occur?
Between two polar molecules
How does PDD arise?
Difference in electronegativity leads to bond polarity
Dipoles don’t cancel out therefore the molecule has an overall permanent dipole
There is an attraction between the delta positive on one molecule and the delta negative on another molecule
When does IDD occur?
Between all molecules but generally non polar molecules
How does IDD arise?
Random movement of electrons in one molecule leads to an
Uneven distribution of electrons creating a
Temporary dipole in one atom, this
Induces a dipole in a neighbouring molecule and
Dipoles attract
When is hydrogen bonding used?
Ice
Proteins
DNA