10/2 notes Flashcards

1
Q

what are the three rules for writing electron configgurations

A

1) Pauli Principle
2)Aufbau Principle
3)Hund’s Rule

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2
Q

Pauli Principle

A

2 electron per orbital max

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3
Q

Aufbau Principle

A

ground state of an atom has the most stable (i.e lowest energy) arrangement of electrons

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4
Q

what does the exponent of 1s^1 refer to

A

number of electrons in the orbital

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5
Q

how many electrons can the p orbital carry

A

six

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6
Q

how to do short cut configuration of writing electron

A

identify element, go up 1 row then all the way right

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7
Q

Hund’s rule

A

for degenerate orbitals, electrons prefer to be in separate orbitals and spin aligned

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8
Q

degenerate

A

same energy

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9
Q

purpose of hund’s rule

A

to minimize electron repulsion and exchange energy (quantum effect)

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10
Q

paramagnetic

A

responds to a magnetic field, net spin is not zero

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11
Q

diamagnetic

A

does not interact with magnetic field, net spin is zero

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12
Q

what is an excited state configuration

A

anything that is not the ground state of an electron configuration of ions

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13
Q

anions

A

add electrons to the lowest available orbitals

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14
Q

cations

A

remove electrons from highest energy orbitals

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15
Q

what is the exception for cations

A

in d block: for d block remove the valence s electrons before the d

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16
Q

isoelectronic

A

have same electron configuration

17
Q

does d block size change

A

does not change much across the row

18
Q

atomic radii size increases

A

down PT

19
Q

atomic radii size decreases

A

right across PT

20
Q

size increases because

A

add new shield of electron that are shielded by core electrons so size increases

21
Q

size decreases because

A

Pull electrons closer by adding protons which is why size decreases

22
Q

exception for Cr

A

[Ar] 4s^1 3d^5

23
Q

exception forCu

A

[Ar] 4s^13d^10