[01] Thermodynamics Flashcards
What is thermodynamics?
A branch of physics that deals with the relationships between heat and other forms of energy.
How many laws of thermodynamics exist?
Four: the zeroth, first, second, and third law.
What does the zeroth law of thermodynamics state?
If two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other.
What does the first law of thermodynamics state?
Energy cannot be created or destroyed, only transformed or transferred (principle of conservation of energy).
What does the second law of thermodynamics state?
The entropy of an isolated system always increases or remains the same; it never decreases (spontaneous processes tend to increase total entropy).
What does the third law of thermodynamics state?
The entropy of a system approaches a constant value as the temperature approaches absolute zero.
What is entropy in thermodynamics?
A measure of the disorder or randomness of a system.
What is the role of a heat engine in thermodynamics?
To convert heat energy into mechanical work.
What is the Carnot cycle?
The most efficient theoretical cycle for heat engines, developed by Sadi Carnot.
What is the concept of absolute zero in thermodynamics?
The lowest possible temperature where nothing could be colder and no heat energy remains in a substance.
What is a thermodynamic system?
A portion of the universe that is being studied for its thermodynamic properties.
What are the types of thermodynamic systems?
- Isolated
- Closed
- Open
What is the difference between endothermic and exothermic processes?
Endothermic processes absorb heat from the surroundings, while exothermic processes release heat to the surroundings.
What is a state function in thermodynamics?
A property that depends only on the current state of the system, not the path taken to get there (examples include energy, enthalpy, and entropy).
What is the principle of equipartition of energy?
The idea that, in a system at thermal equilibrium, each degree of freedom will have the same amount of energy.