week 5 - physical and chemical properties of seawater Flashcards

1
Q

properties of seawater (8 things)

A
  1. water
  2. temperature
  3. salinity
  4. density
  5. carbon dioxide
  6. acidity and alkalinity (pH)
  7. the carbonate buffer system
  8. chemical residence time
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2
Q

salinity and pH of seawater

A

salinity of 35 PSU and pH of 7.5 to 8.4

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3
Q

polarity

A

has a positive charge on one end of a molecule and negative charge on the other
- results in high latent heats of melting and vaporization

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4
Q

hydrogen bonds during heating (melting)

A

some break away from each other

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5
Q

hydrogen bonds in ice

A

lots of packed bonds

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6
Q

hydrogen bonds during vaporization (gas)

A

all of the bonds break

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7
Q

how is seawater different from regular water?

A

seawater has a high salinity
- proportion of ions is constant no matter where you get the water from

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8
Q

how to find total salinity

A

1.80555 x ionic abundance

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9
Q

what is temperature in relation to seawater

A

a measure of the amount of heat stored in the ocean
- affects density (the higher the temperature of the water, the lower the density)
- oceans store a lot of energy because of the high heat capacity

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10
Q

salinity

A

the salt content of seawater that is expressed in the concentration of ions in seawater

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11
Q

how does the salinity of seawater increase?

A

whenever pure water is removed by evaporation or the formation of ice

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12
Q

how does the salinity of seawater decrease?

A

when water is added by precipitation or the melting of ice

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13
Q

inorganic components in seawater

A
  1. chloride (CI-)
  2. sodium (NA+)
  3. sulfate (SO42)
  4. magnesium (MG2+)
  5. calclium (CA2+)
  6. potassium (K+)
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14
Q

factors that change the salinity of seawater

A
  1. evaporation of water and formation of ice increase salinity
  2. precipitation and ice melting (adding water) decreases salinity
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15
Q

with increasing salinity (3 things)

A
  1. density of water increases
  2. boiling point of water increases
  3. freezing point of water decreases
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16
Q

density in relation to seawater

A
  1. coldest waters are usually the most dense
  2. high density is favored by low temperature and high salinity
17
Q

CO2 in relation to seawater

A
  1. highly soluble in seawater because it creates carbonic acid
18
Q

dissolved organic carbon (DIC)

A

when carbonic acid dissociates to form hydrogen and bicarbonate ions, which then dissociates to form hydrogen and carbonate ions
- most of carbon dioxide in the oceans is stored in bicarbonate ions

19
Q

acids

A

any compounds that when dissolved in water, releases hydrogen ions (H+, also called protons) which increases their concentration in solution

20
Q

what makes pH neutral

A

when concentration of protons and hydrogen ions are equal in pure water

21
Q

what happens when we dissolve acid in water?

A

the hydrogen ion concentration will increase as the acid dissociates

22
Q

alkaline substance (base)

A

dissociates in water, releasing hydroxyl ions (OH-) into the solution

23
Q

pH system

A

ranges from 0 to 14
- pure water has a neutral pH with a value of 7
- acidic solutions have extra H+ and has a value of LESS than 7
- alkaline (basic solutions) has pH values GREATER than 7
- when concentration goes down 1 level, the concentration goes up by ten

24
Q

what happens when you add acid to water?

A

H reacts with bicarbonate and makes carbonic acid

25
Q

what happens when you add alkaline to water?

A

OH- reacts with carbonic acid which makes bicarbonate

26
Q

chemical residence time

A

the average length of time an element spends in the ocean between its addition and removal

amount of element in ocean/elements rate of removal (or addition from the ocean)