Water of crystallisation Flashcards
What happens when salts dissolve in water?
Ions in its lattice separate and are surrounded by a sphere of water molecules (become hydrated ions)
What happens during crystallisation?
Water molecules evaporate off, and electrostatic attraction pulls the ions together to form a crystal lattice
What is water of crystallisation?
Water molecules bonded into a salt’s solid crystal structure. They did not evaporate when substance was heated, so stayed in the crystal lattice
Why does water of crystallisation have more mass?
Also involves the mass of the bonded water molecules
What is a hydrated salt?
A solid salt containing water of crystallisation
What is an anhydrous salt?
A salt not containing water of crystallisation
How is water of crystallisation represented?
a dot then H2O - that many water molecules per formula unit (x if unknown)
How do you turn hydrated salts into anhydrous salts?
Vigorous heating
How do you turn anhydrous salts into hydrated salts?
Cannot do it in one step because:
- It requires an exact amount of water
- Can’t ensure exact amount of added water will be evenly distributed throughout the sample
- A small amount of anhydrous salt will dissolve in the water
What are anhydrous salts used for?
Drying agents (to remove some water from a sample), and to test for water - if dissolves to form blue solution or forms blue solid, sample has water. If it remains a white powder, sample does not have water