Ionisation energy (not incl. the graphs) Flashcards
Define first ionisation energy
Energy required to remove one electron from each atom in 1 mole of gaseous atoms to form 1 mole of gaseous 1+ ions
What happens to nuclear charge across the period?
Increases due to there being more protons
What happens to atomic radius when nuclear charge increases?
Electrons pulled closer to nucleus, decreasing atomic radius
What happens to first ionisation energy as atomic radius decreases?
Increases
What does a high ionisation energy mean?
High attraction between electrons and nucleus so more energy needed to remove electron
Why does ionisation energy decrease down a group?
Atomic radius increases and greater shielding from inner shells
Why does group 6 have a lower ionisation energy then group 5 (in the same period)
Group 6 - electron removed from orbital with two electrons, so there’s repulsion (easier to move)
Why does group 3 have a lower ionisation energy than group 2 (in the same period)?
Group 3 - outermost electron in p-orbital which has high energy so electron is further from nucleus
Group 2 - outermost electron in s-orbital (lower energy level)