water Flashcards

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1
Q

geometry of water

A

tetrahedral

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2
Q

the ideal angle of tetrahedral is ___ degrees, but repulsion of e- from H pushes H together to ___ degrees

A

109.5; 104.5

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3
Q

each water molecule can form H bonds with ___ other water cules to form an inter-molecular network

A

4

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4
Q

H-bonds hold water molecules ___% closer together than without H-bonds

A

15

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5
Q

the anomalous properties of H2O are due to its _____ H-bonds

A

intra-molecular

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6
Q

why are H2O MP and BP so unusually high?

A

because of the H bonds

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7
Q

why does top freeze and bottom remain liquid?

A

because the bottom is 4 degrees, which is heaviest, so it stays at the bottom; meanwhile ice volume is larger, it floats on top

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8
Q

what is phase transition?

A

the transformation of a thermodynamic system from one phase to another

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9
Q

what are the 5 different phases of water?

A

liquid, vapour, solid, glass, supercritical fluid

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10
Q

food with aw > ___ and pH > ___ are regarded as potentially hazardous

A

0.85; 4.6

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11
Q

what are humactants?

A

salts, sugars, glycerol that prevent moisture migration from high water activity bread to the fillings

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12
Q

army rations are baked at ____ F

A

185

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13
Q

what is the latent heat of vapourization of water?

A

540 cal/g

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14
Q

what is the latent heat of fusion of ice?

A

80 cal/g

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15
Q

what do the colligative properties of water solely depend on?

A

the number of solute molecules dissolved

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16
Q

dissolving of solute ___ vapour pressure, ___ freezing point, ____ boiling point

A

lowers; lowers; raises

17
Q

how is water activity calculated?

A

aw=vapour pressure of food (p)/vapour pressure of pure water (po)

18
Q

what are the three states of water in food?

A

bound, capillary, free

19
Q

these graphs of data show relation between aw and moisture content:

A

moisture sorption isotherm