VSEPR Flashcards
valence shell electron pair repulsion theory
predicts shapes of molecules and atoms by assuming that valence shell electron pairs are arranged around so that electron pairs are kept as far away from each other as possible. Double or triple bonds will not change this.
Dipole moment
Arrows that point to the more electronegative ion. If they oppose, they cancel out. If they go towards each other, they add together.
Molecules with zero dipole moments are non polar
Polar molecules
Non symmetrical, with a dipole moment
Bond theory
Bonds form when two orbitals overlap
Total number of electrons in each orbital is no more than two
Strength of the bonds depends on the amount of overlap, orbitals bond in the directions in which they protrude a point to obtain maximum overlap
Hybrid orbitals
Orbitals used to describe bonding that are obtained by taking combinations of atomic orbitals. Number of hybrid orbitals is always equal to the number of orbitals used
sp shape
Linear
sp2 shape
trigonal planar
sp3 shape
tetrahedral
sp3d
trigonal biprymidal
2p3d2
Octahedral
Sigma bonds
Formed when there is a single bond, when two 2 orbitals overlap
Pi bonds
Electron distribution above and below the bond axis- formed by a sideways gap of 2 p orbitals. Will have a sigma bond with it
Diatomic molecules
Non polar if the two atoms are identical
Polar if they are different
Triatomic molecules
If they are linear with the same atoms bonded to the central atom, non polar
if terminal atoms are different they are polar
If the molecule is bent, it is polar
Steric number
The number of atoms bonded to an electron