Volumetric Method Flashcards

1
Q

The determination of the volumeof a
solution of known concentration required to
react with a given amount of a substance to
be analyzed.

A

Volumetric Method

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2
Q

Acid and base combine to form SALT and WATER

A

NEUTRALIZATION

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3
Q

The 3 principle involved in volumetric method neutralization

A

Precipitation, Complexation, REDOX

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4
Q

the chemical substance being analyzed or the
active constituentin the sample.

A

Analyte /titrand

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5
Q

one which concentration is accurately known.- written using 4 decimal places

A

Standard solution(titrant or Volumetric Solution)

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6
Q

process by which a standard solution is brought
into reaction until the desired reaction is
accomplished

A

Titration

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7
Q

a chemical which changes color at or very near
the endpoint.

A

Indicator/ Test solution

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8
Q

Reagents in such
solvents and of such
definite concentrations
that it will suitable for
specified purpose

A

Test solution (indicator)

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9
Q

Usual concentration is _______,
with _______ of indicator
used for ____ of the analyte.

A

0.05% (1)
0.1 to 0.2 ml (2)
10 ml (3)

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10
Q

shown by the change of color of the indicator. can be seen by a naked eye

A

Endpoint / practical

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11
Q

is the theoretical point at which equivalent amounts of each substance have reacted

A

Equivalence point/ stoichiometric point /theoretical endpoint

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12
Q

(ph range) 0 –2.0
(Acid ) Yellow
(Base) Green

A

Malachite Green

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13
Q

(ph range) 3.2 -4.4
(Acid ) Pink
(Base) Yellow

A

Methyl orange

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14
Q

(ph range) 4.2 –6.2
(Acid ) Red
(Base) Yellow

A

Methyl Red

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15
Q

(ph range) 6.0 –7.6
(Acid ) Yellow
(Base) Blue

A

Bromothymol blue

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16
Q

(ph range) 8 -10
(Acid ) Colorless
(Base) Pink or red

A

Phenolphthalein

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17
Q

(ph range) 8 –9.2
(Acid ) yellow
(Base) blue

A

Thymol blue

18
Q

_________follow the color of acids

A

Methyl Red and methyl orange

19
Q

_________ follow the color of bases

A

Malachite green, bromothymol blue and thymol blue

20
Q

When weak acid is titrated with strong alkali,
use ???

A

phenolphthalein

21
Q

When weak alkali is titrated with strong acid,
use ???

A

methyl red

22
Q

When a strong acidis titrated with a strong alkali, ???

A

methyl red, methyl orange or Pp may be used

23
Q

____ should never be titrated with _____ indicator will not give a sharp endpoint

A

Weak alkali (1)
weak acid (2)

24
Q

Precipitation indicator

A

common: silver nitrate (AgNO3)
*Dichlorofluorescein
*Eosin Y
*Potassium chromate
*FAS (Ferrous Ammonium Sulfate)

25
Q

Complexometry indicator

A

common: EDTA/ Ethylene diamine tetraacetic acid
* Dithiazone
*Eriochrome black
*Hydroxynaphthol blue

26
Q

REDOX indicator

A

*Iodine TS
*Potassium
permanganate VS
*Starch TS

27
Q

number of moles of reactive unit in a compound
that which reacts or takes the place of one mole of Hydrogen ion

ACIDS/Bases -# of H or OH
Salts –Valence of cation

A

Equivalent

28
Q

mass of one equivalent
*weight that is chemically equivalent to the reacting
power of one of one atomic weight of hydrogen

A

Equivalent weight

29
Q

Strength in grams equivalent to milliliter of
standard solution or the weight of a substance
chemically equivalent to 1 ml of a standard
solution.

A

TITER

30
Q

contains one gram equivalent weight of solute in a liter of
solution or one gram milliequivalent weight in a milliliter of solution.

A

Normality/ Normal solution

31
Q

contains a mole (one gram molecular
weight) in a liter of solution or one millimole per
milliliter of solution. A moleis the molecular weight
expressed in grams. A millimoleis one thousandth part of
a mole.

A

Molarity

32
Q

a section of chemistry that involves using relationships between reactants and/or products in a chemical reaction to determine desired quantitative data.

A

Stoichiometry

33
Q

Knowing EXACTLY
what the concentration
of the solution

Process of determining exact concentration
of a solution.

A

Standardization

34
Q

2 Types of Volumetric solutions:

A

Primary standard
Secondary standard

35
Q

-chemically pure solid substance almost
99.9% pure used in the standardization of a
solution

A

Primary Standard

36
Q

Primary Standard for acid solutions?

A

Anhydrous pure sodium carbonate Calcium carbonate
THAM
(trihydroxymethylaminomethane)

37
Q

Primary Standard for alkali solutions

A

benzoic acid,
potassium biphthalate
sulfamic

38
Q

Substance that is not necessarily pure
but whose exact purity is known.
*A standard solution is a commonly used
______

A

Secondary Standard

39
Q

acid burette is also known as?
provide three-way stopcocks for easier fill

A

Geissler burette

40
Q

burettes do not have stopcocks at their tips and use to hold a base titrant

A

Mohr burette

41
Q

part of volumetric analysis whereby an acid solution at known concentration, along with a specific indicator, is used to titrate a base solution and thus work out its concentration“.

titrant: acid
analyte: Base

A

Acidimetry

42
Q

part of volumetric chemical analysis which enables us to work out the concentration of an acid solution using an alkaline solution at a known concentration and a suitable indicator.

titrant: Base
analyte: Acid

A

alkalimetry