Unit 4 Atomic History Flashcards

1
Q

Democritus

A
  • Proposed the idea of atoms as the smallest undividiable particle of a substance.
  • Stated that all the universe is composed of two elements: the atoms and the void in which they exist
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2
Q

John Dalton

A
  • Developed an “atomic theory” with spherical solid atoms based upon measurable properties of mass
    • Atoms make up everything and cannot be created or destroyed.
    • Atoms of an element are identical.
    • Atoms are rearranged in chemical reactions to form different substances.
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3
Q

Sir William Crookes

A
  • Discovered
    • cathode rays travel in straight lines
    • cause glass to fluoresce
    • give a negative charge to objects they strike
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4
Q

J.J. Thomson

A
  • Discovered/proved the electron
  • Used a CRT to experimentally determine the charge to mass ratio (e/m) of an electron =1.759 x 10 8 coulombs/gram
  • Also studied “canal rays” and found they were associated with the proton ( H+)
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5
Q

Ernest Rutherford

A
  • Studied radiations emitted from uranium and thorium and named them alpha and beta
  • Gold Foil experiement
  • Using alpha particles as atomic bullets, discovered the nucleus and established that the nucleus was
    • very dense
    • very small
    • positively charged
  • Disproved the Plum Pudding Model (assumed that the electrons were located outside the nucleus)
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6
Q

Max Planck

A
  • used the idea of quanta (discrete units of energy) to explain hot glowing matter
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7
Q

Hantaro Nagaoka

A
  • Proposed a “Saturnian” model of the atom with flat rings of electrons revolving around a positively charged particle
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8
Q

R.A. Millikan

A
  • Oil drop experiment determined the charge (e=1.602 x 10 -19 coulomb) and the mass (m = 9.11 x 10 -28 gram) of an electron.
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9
Q

H.G.J. Moseley

A
  • Using x-ray tubes, determined the charges on the nuclei of most atoms
  • wrote “The atomic number of an element is equal to the number of protons in the nucleus”
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10
Q

Niels Bohr

A
  • Developed an explanation of atomic structure that underlies regularities of the periodic table of elements;
  • Developed Bohr model (planetary model) - had atoms built up of sucessive orbital shells of electrons
  • Proposed energy levels for electrons
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11
Q

Louis de Broglie

A
  • Discovered that electrons had a dual nature-similar to both particles and waves (Particle/wave duality)
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12
Q

Werner Heisenberg

A
  • Described atoms by means of formula connected to the frequencies of spectral lines.
  • Proposed Principle of Indeterminancy (Heisenberg Uncertainty Principle) - you can not know both the position and velocity of a particle
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13
Q

Erwin Schrodinger

A
  • Viewed electrons as continuous clouds
  • Introduced “wave mechanics” as a mathematical model of the atom
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14
Q

James Chadwick

A
  • Using alpha particles discovered the neutron
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15
Q

s sublevel

A

Has one orbital

Present on every energy level

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16
Q

p sublevel

A

3 orbitals

appears for the first time on 2nd energy level

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17
Q

d sublevel

A

5 orbitals

appears for the first time on 3rd energy level

always fills after the s on the level above (4s and then 3d)

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18
Q

f sublevel

A

7 orbitals

appears for the first time on 4th energy level

fills after the s orbital two energy levels above

(4f fills immediately after 6s)

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19
Q

cation

A

ion with a positive charge

usually a metal ion

20
Q

anion

A

ion with a negative charge

usually a nonmetal

21
Q

speed of light

A

3.0 x 108 m/s

22
Q

Planck’s constant

A

6.626 x 10-34

23
Q

Aufbau Principle

A

Electrons are added to an atom in order of increasing energy.

24
Q

Hund’s Rule

A

One electron is added to all orbitals within a sublevel before a second electron is added to any orbital.

25
Q

Pauli Exclusion Principle

A

Two electrons occupying the same orbital must have opposite spins.

26
Q

Mass of proton

A

1 amu

27
Q

Mass of neutron

A

1 amu

28
Q

Mass of electron

A

0 amu

29
Q

Charge of Proton

A

+1

30
Q

Charge of electron

A

-1

31
Q

Charge of neutron

A

0

32
Q

Location of protons

A

Nucleus

33
Q

Location of Neutrons

A

Nucleus

34
Q

Location of Electrons

A

Electron cloud or Energy Levels or Orbits

35
Q

Protons determine __________

A

identity of the element

36
Q

Neutrons determine ________

A

which isotope of the element.

37
Q

Electrons determine __________

A

the charge (the ion of the element)

38
Q

First quantum number

(Principal quantum number)

A

n, describes the energy level the electron is on

39
Q

Second quantum number

(angular quantum number)

A

Describes the shape of the orbital (s, p, d, f)

40
Q

Allowed third quantum numbers for s

A

0

41
Q

Allowed third quantum numbers for p

A

-1, 0, +1

42
Q

Allowed third quantum numbers for d

A

-2, -1, 0, 1, 2

43
Q

Allowed third quantum numbers for f

A

-3, -2, -1, 0, +1, +2, +3

44
Q

Third quantum number

A

Describes the orientation of the orbital within the sublevel (which blank)

45
Q

Second quantum number values for each sublevel

A

s = 0

p = 1

d = 2

f = 3

46
Q

Fourth quantum number

A

describes spin of an electron

First electron in orbital (blank) = +1/2

Second electron in orbail (blank) = -1/2