Unit 3: 4 - Analysis and Synthesis Flashcards
What colour is the flame when you put Lithium (L+) ions into the flame?
Crimson red.
What colour is the flame when you put Sodium (Na+) ions into the flame?
Yellow.
What colour is the flame when you put Potassium (K+) ions into the flame?
Lilac.
What colour is the flame when you put Calcium (Ca2+) ions into the flame?
Red.
What colour is the flame when you put Barium (Ba2+) ions into the flame?
Green.
What is special about the hydroxides of metals with ions that have a +2 or +3 charge?
They are insoluble in water.
What is special about adding excess sodium hydroxide to aluminium hydroxide compared to adding excess to calcium or magnesium hydroxide?
Aluminium hydroxide dissolves, whereas the others do not.
What colour precipitates do aluminium, calcium and magnesium ions form (when mixed with NaOH)?
White.
Give a balanced ionic equation for the reaction of Iron (III) ions with hydroxide ions.
Fe3+(aq) + 3OH-(aq) → Fe(OH)3(s)
How do you test for carbonate ions?
Add dilute hydrochloric acid to the substance. If effervescence occurs, bubble the gas through limewater. If it turns cloudy, the substance contains carbonate ions.
Write a balanced equation for the reaction of calcium carbonate with dilute hydrochloric acid.
2HCl(aq) + CaCO3(s) → CaCl2(aq) + H2O(l) + CO2(g)
How do we test a solution for halide ions? Give the results for chloride ions, bromide ions and iodide ions.
Add dilute nitric acid and then silver nitrate to the solution.
- Bromide ions give you a cream precipitate;
- Chloride ions give you a white precipitate;
- Iodide ions give you a yellow precipitate.
How do we test a solution for sulphate ions?
Add dilute hydrochloric acid and then barium chloride solution. If a white precipitate forms, sulphate ions are present.
Why must we use nitric acid first instead of other acids when testing for halides?
Nitric acid removes interfering ions first (like carbonate ions), and if you used acid like HCl, then it would not react with chlorine.
What is a qualitative analysis?
An analysis which simply determines whether or not a substance is in a sample.