Unit 2 Topic 2 ✓ Flashcards
Physical Chemistry: Acids and Bases
What is a Dative bond?
(Also known as a Coordinate bond)
A dative bond is a covalent bond in which one of the atoms supplies both of the electrons
According to Bronsted-Lowry theory:
What is an Acid?
An acid is a proton donor
NOTE: A proton is a hydrogen ion
According to Bronsted-Lowry theory:
What is a Base?
A base is a proton acceptor
NOTE: A proton is a hydrogen ion
What is a Conjugate base?
A conjugate base is the substance that is left behind after an acid has donated its proton
NOTE: The stronger the acid, the weaker the conjugate base
What is an Amphoteric susbtance?
An amphoteric substance is a substance that can react as an acid or a base
e.g. Water
What is pH?
pH is the ‘potential of hydrogen’
-it measures [hydronium] in solution
NOTE: square brackets [ ] = concentration
As the concentration of hydronium increases, the pH decreases
What is pOH?
pOH is the ‘potential of hydroxide’
-it measures [OH]
What is a Strong acid?
A strong acid is an acid that completely dissociates into ions in solution
High acid dissociation content (Ka)
e.g. Hydrochloric acid, Nitric acid, Sulfuric acid
NOTE: Diluting a strong acid by a factor of 10, changes its pH by 1
What is a Weak acid?
A weak acid is an acid that only partially dissociates into ions in solution
Low acid dissociattion content (Ka)
e.g. Ethanoic acid (most organic acids)
NOTE: Diluting a weak acid by a factor of 10, changes it pH by 0.5
What is a Polyprotic acid?
A polyprotic acid is an acid with more than one ionisible proton
NOTE: Each ionisible proton is removed one by one
What does Equimolar mean?
Equimolar means that two substances have an equal number of moles
What does a Monoprotic acid mean?
Monoprotic means that an acid has one transferrable proton per molecule
(Diprotic means two protons are transferable)
What is a Strong base?
A strong base is a base that ionises completely in solution
e.g. Potassium hydroxide, potassium oxide etc.
NOTE: A strong base doesn’t need to contain hydroxide ions as it can gain them from the solution
What is a Weak base?
A weak base is a base that only partially dissociates into ions in solution
e.g. Ammonia and amines
What is a Salt?
A salt is a substance that is produced when the proton of an acid is replaced by a positive ion
NOTE: The positive ion is usually a metal or an ammonium ion
When using an Indicator -
What is the End point of a titration reaction?
The end point of a titration reaction is the point that is shown by a change in indicator colour
What is the Equivalence point of a neutralisation reaction?
The equivalence point of a neutralisation reaction is the point when the moles of base = moles of acid, so the solution only contains salt and water
What are Indicators?
Indicators are weak acids that change colour in response to pH
What is a Buffer solution?
A buffer solution is a solution in which the pH remains approximately constant when small volumes of acid/base/water are added
NOTE: If a large amount is added, pH wont remain consistent
What is an Acid buffer?
An acid buffer is a buffer made up of a weak acid and one of it’s salts from a strong base
e.g. Sodium hydroxide or Potassium Hydroxide
What is a Basic buffer?
A basic buffer is a solution consiting of a weak base and one of it’s salts
e.g. Ammonium chloride