Unit 2 Topic 2 ✓ Flashcards

Physical Chemistry: Acids and Bases

1
Q

What is a Dative bond?

(Also known as a Coordinate bond)

A

A dative bond is a covalent bond in which one of the atoms supplies both of the electrons

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2
Q

According to Bronsted-Lowry theory:

What is an Acid?

A

An acid is a proton donor

NOTE: A proton is a hydrogen ion

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3
Q

According to Bronsted-Lowry theory:

What is a Base?

A

A base is a proton acceptor

NOTE: A proton is a hydrogen ion

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4
Q

What is a Conjugate base?

A

A conjugate base is the substance that is left behind after an acid has donated its proton

NOTE: The stronger the acid, the weaker the conjugate base

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5
Q

What is an Amphoteric susbtance?

A

An amphoteric substance is a substance that can react as an acid or a base

e.g. Water

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6
Q

What is pH?

A

pH is the ‘potential of hydrogen’
-it measures [hydronium] in solution

NOTE: square brackets [ ] = concentration

As the concentration of hydronium increases, the pH decreases

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7
Q

What is pOH?

A

pOH is the ‘potential of hydroxide’
-it measures [OH]

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8
Q

What is a Strong acid?

A

A strong acid is an acid that completely dissociates into ions in solution
High acid dissociation content (Ka)

e.g. Hydrochloric acid, Nitric acid, Sulfuric acid

NOTE: Diluting a strong acid by a factor of 10, changes its pH by 1

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9
Q

What is a Weak acid?

A

A weak acid is an acid that only partially dissociates into ions in solution
Low acid dissociattion content (Ka)

e.g. Ethanoic acid (most organic acids)

NOTE: Diluting a weak acid by a factor of 10, changes it pH by 0.5

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10
Q

What is a Polyprotic acid?

A

A polyprotic acid is an acid with more than one ionisible proton

NOTE: Each ionisible proton is removed one by one

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11
Q

What does Equimolar mean?

A

Equimolar means that two substances have an equal number of moles

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12
Q

What does a Monoprotic acid mean?

A

Monoprotic means that an acid has one transferrable proton per molecule

(Diprotic means two protons are transferable)

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13
Q

What is a Strong base?

A

A strong base is a base that ionises completely in solution

e.g. Potassium hydroxide, potassium oxide etc.

NOTE: A strong base doesn’t need to contain hydroxide ions as it can gain them from the solution

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14
Q

What is a Weak base?

A

A weak base is a base that only partially dissociates into ions in solution

e.g. Ammonia and amines

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15
Q

What is a Salt?

A

A salt is a substance that is produced when the proton of an acid is replaced by a positive ion

NOTE: The positive ion is usually a metal or an ammonium ion

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16
Q

When using an Indicator -

What is the End point of a titration reaction?

A

The end point of a titration reaction is the point that is shown by a change in indicator colour

17
Q

What is the Equivalence point of a neutralisation reaction?

A

The equivalence point of a neutralisation reaction is the point when the moles of base = moles of acid, so the solution only contains salt and water

18
Q

What are Indicators?

A

Indicators are weak acids that change colour in response to pH

19
Q

What is a Buffer solution?

A

A buffer solution is a solution in which the pH remains approximately constant when small volumes of acid/base/water are added

NOTE: If a large amount is added, pH wont remain consistent

20
Q

What is an Acid buffer?

A

An acid buffer is a buffer made up of a weak acid and one of it’s salts from a strong base

e.g. Sodium hydroxide or Potassium Hydroxide

21
Q

What is a Basic buffer?

A

A basic buffer is a solution consiting of a weak base and one of it’s salts

e.g. Ammonium chloride