U2 P6 - oxidation of food Flashcards
oxidation reactions
oxygen molecules from the air damage the structure of the fat/oil causing degradation of long fatty acid chains and formation of short-chain oxidation products
antioxidants
molecules that prevent unwanted oxidation reactions occurring
they oxidise in place of the compound they have been added to protect
they are reducing agents
how do antioxidants work
antioxidants ‘mop-up’ free radicals and protect the food by donating an electron to the free radical
this forms a stable pair of electrons, stabilising the free radical
during this process the antioxidant molecules becomes oxidised as it loses an electron
oxidation is an ….. in the oxygen to hydrogen ratio
increase
reduction is an ….. in the oxygen to hydrogen ratio
decrease
oxidation of aldehydes
primary alcohol->aldehydes->carboxyllic acids
secondary alcohol-> ketones
tertiary alcohols do not oxidise
oxidation of ketones
do not oxidise
oxidising agents
hot copper
fehlings solution
tollens reagent
acidified dichromate