U2 P4 - soaps, detergents + emulsions Flashcards
fats + oils
can be used to make soaps, detergents + emulsions
saponification
the process of making soap by hydrolysing edible oil using an alkaline solution
fatty acid + sodium hydroxide —> soap + water
soaps
sodium salts of fatty acids
detergents
compounds with a soap-like structure
non-polar tail which is oil soluble and a and a polar which is water-soluble
difference between detergent head + soap head
detergent - sulphonate head
soap - carboxylate head
structure of soaps
long covalent hydrocarbon tail which is soluble in non-polar compounds - hydrophobic
polar ionic charged head which is water-soluble - hydrophilic
cleansing mechanism of soaps
hydrophobic tail burrows into droplet of oil/grease
hydrophilic heads are left to face the surrounding water
this results in formation of a ball-like structure
non-polar substance such as oil/grease are held inside the ball and suspended in water to be washed away
emulsions
liquids which contain small droplets of another liquid, usually separates into 2 layers
role of emulsifier
keeps water-soluble and oil-soluble compounds together
have a non polar and polar part
formation of emulsifier
reacting edible oils with glycerol
emulsifier structure
hydroxyl groups are hydrophilic
fatty acid chains are hydrophobic
fatty acid chain therefore dissolves in oil whilst the hydroxyl groups dissolves in water, forming a stable emulsion