Transition Metals Flashcards

1
Q

What makes a transtition metal a transition metal?

A

It has an incomplete d subshell

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2
Q

why is zinc not a transition metal?

A

It has a complete d subshell.

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3
Q

What is a complex?

A

A central metal surrounded by ligands.

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4
Q

What is a ligand?

A

A species which can donate a lone electron pair

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5
Q

what is the type of bond formed between the metal ion and the ligand?

A

Dative covalent

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6
Q

What is coordination number?

A

Number of bonds to central metal ion

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7
Q

what does monodentate mean?

A

Can form one coordinate bond per ligand

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8
Q

What to look for when doing a substitution reaction?

A

number of ligands
coordination number of each ligand
what is the size of each ligand
what is the charge of each each ligand
dont forget your extra product/s

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9
Q

why do chloride ions only form 4 bonds?

A

When substituting chloride ions they will only form 4 coordinate bonds because they are large ions.

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10
Q

What is the charge of EDTA?

A

4-

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11
Q

Why does substituting a monodentate with a bidentate ligand make it more stable?

A

Positive entropy change as there are more molecules of products than reactants

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12
Q

What is the use of EDTA?

A

To remove heavy metal ions from water and in shampoos to remove calcium.

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13
Q

What three things arise colour change?

A

oxidation number
coordination number
ligand

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13
Q

What three things arise colour change?

A

oxidation number
coordination number
ligand

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14
Q

What are the ions of scandium colour?

A

no colour

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15
Q

Determining the concentration of a complex ion?

A

add ligand to intensify colour
make up solutions of known concentrations
measure absorbtion with spectrometer
plot graph
interpolate with unknown substance

16
Q

What happens to the relative stability of the +2 and +3 transition metal ions as you progress along the period?

A

The relative stability of +2 increases across the period with respect to the +3 state.

17
Q

what do transition metals with high and low oxidation states tend to be?

A

High is oxidising agent and low is reducing agent?

18
Q

What acid do you use for manganate titrations?

A

Only sulphuric

19
Q

Why would using an insufficient amount of sulphuric acid produce an inaccurate reading of the volume of manganate being used?

A

Brown MnO2 will form which masks the colour change.

20
Q

Why would using an insufficient amount of sulphuric acid produce an inaccurate reading of the volume of manganate being used?

A

Brown MnO2 will form which masks the colour change.

21
Q

What is the catalyst being used in the manufacturing of methanol from carbon monoxide and water?

A

Cr2O3