Transition Elements: Properties Flashcards

1
Q

what are transition elements?

A
  • d-block elements that have an ion with an incomplete d sub shell(partially filled)
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2
Q

what is a d block element?

A
  • an element that has its highest energy electron in d subshell
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3
Q

what elements in the d block cannot be transition elements?

A
  • scandium
  • zinc
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4
Q

why can’t scandium be a transition element?

A
  • scandium does not form ions with partially filled d orbitals
  • d sub shell is completely empty
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5
Q

why can’t zinc be a transition element?

A
  • zinc does not form ions with partially filled d orbitals
  • the d subshell is completely full
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6
Q

what are the three main properties of transition elements?

A
  • form coloured compounds
  • elements and their compounds act as catalysts
  • form compounds, in which the transition element has different oxidation states
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7
Q

why can transition elements be catalysts?

A
  • provide a good surface area on which the reaction can take place
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8
Q

what are example of transition elements as catalyts?

A
  • Haber Process = iron metal catalyst
  • Contact process = V2O5 catalyst
  • hydrogenation of alkenes: = nickel metal catalyst
  • decomposition of hydrogen peroxide = MnO2(managanese dioxide)
  • Zn with acids = Cu2+, copper sulfate
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9
Q

what are the exceptions involved in the electronic configurations of transition elements?

A
  • chromium
  • copper
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10
Q

what is the electronic configuration of chromium?

A

1s2,2s2,2p6,3s2,3p6,3d5,4s1

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11
Q

what is the electronic configuration of copper?

A

1s2,2s2,2p6,3s2,3p6,3d10,4s1

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