Topic 16: Further kinetics Flashcards
rate of reaction is
the change in concentration of a species divided by the time it takes for the change to occur. all reaction rates are positive
the rate equation is
an equation expressing the mathematical relationship between the rate of reaction and the concentrations of the reactants
the order of a reactant species is
the power to which the concentration of the species is raised in the rate equation (or the coefficient of the species in the stoichiometric equation
the overall order of a reaction is
the sum of all the individual orders
the rate-determining step of a reaction is
the slowest step in the mechanism for the reaction
the half-life of a reaction is
the time taken for the concentration of the reactant to fall to one-half of its initial value
the instantaneous reaction rate is
the gradient of a tangent drawn to the line of the graph of concentration against time. the instantaneous rate varies as the reaction proceeds (except for a zero order reaction)