Topic 15: Transition metals Flashcards

1
Q

a transition metal is

A

an element that forms one or more stable ions with incompletely filled d-orbitals

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2
Q

a ligand is

A

a species that uses a lone pair of electrons to form a dative bond with a metal ion

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3
Q

a complex is

A

a species containing a metal ion joined to ligands

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4
Q

a complex ion is

A

a complex with an overall positive or negative charge

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5
Q

the coordination number is

A

the number of dative bonds in the complex

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6
Q

the electromagnetic spectrum is

A

the range of all wavelengths and frequencies of all the types of radiation

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7
Q

complementary colours are

A

colours opposite each other on a colour wheel

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8
Q

six-fold coordination refers to

A

complexes in which there are six ligands forming coordinate bonds with the transition metal ion

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9
Q

a square planar shape contains

A

contains a central atom or ion surrounded by four atoms or ligands in the same plane and with bond angles of 90 degrees

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10
Q

a monodentate ligand is

A

one that forms one dative bond with a metal ion

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11
Q

a bidendate ligand is

A

one that forms two dative bonds with a metal ion

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12
Q

a multidentate ligand is

A

one that forms several dative bonds with a metal ion

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13
Q

amphoteric behaviour refers to

A

refers to the ability of a species to react with both acids and bases

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14
Q

a heterogeneous catalyst is

A

one that is in a different phase from the reactants

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15
Q

adsorption is

A

the process that occurs when reactants form weak bonds with a solid catalyst

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16
Q

desorption is

A

the process that occurs when products leave the surface of a solid catalyst

17
Q

a homogeneous catalyst is

A

one that is in the same phase as the reactants

18
Q

autocatalysis occurs when

A

when a reaction product acts as a catalyst for the reaction

19
Q

a catalyst is

A

a substance that increases the rate of a chemical reaction by providing an alternative reaction pathway with lower activation energy, but is chemically unchanged at the end of the reaction