Topic 10-Equilibrium I Flashcards

1
Q

What is a homogeneous system?

A

A system in which everything is in the same physical state.

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2
Q

What is a heterogenous system?

A

Where not everything is in the same physical state. (therefore leave out solids and liquids)

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3
Q

If value of Kc is less than 1 what does this mean?

A

Position of equilibrium lies to the left

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4
Q

If value of Kc is more than 1 what does this mean?

A

Position of equilibrium lies to the right

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5
Q

Equation for mole fraction?

A

no.of moles in gas /total no.of moles of all gases

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6
Q

Equation for partial pressure?

A

total pressure * mole fraction

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7
Q

Explain “dynamic equilibrium” (2)

A

Forward reaction= same rate as backward reaction

The concentrations of reactants and products stay constant (closed system)

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8
Q

Catalysts …. …. the equilibrium constant or concentrations.

A

Catalysts don’t affect the equilibrium constant or concentrations of products or reactants.

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9
Q

Catalysts speed up the … of …. ……. being reached

A

Catalysts speed up the rate of Dynamic Equilibrium being reached.

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10
Q

If there’s a change in ……., ……… or …………. the equilibrium will …… to ……… the change.

A

If there’s a change in pressure, concentration or temperature the equilibrium will move to counteract that change.

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11
Q

What condition effects the values of Kc?

A

Temperature

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12
Q

What is Le Chatelier’s Principle?

A

When a change occurs in a system the equilibrium position will move to help counteract the change

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13
Q

Increasing ​temperature favours the​ ……. reaction​

A

endothermic

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14
Q

decreasing​ temperature favours the ​……. reaction

A

exothermic

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15
Q

Increasing​ pressure favours the side of the reaction with ​….. ……​

A

fewer moles

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16
Q

​decreasing​ pressure favours the side of the reaction with …… …..​

A

more moles

17
Q

If temperature is decreased the equilibrium will shift to oppose this and move in the …….. direction to try to increase the temperature by giving out heat.

A

EXOTHERMIC

18
Q

If temperature is increased the equilibrium will shift to oppose this and move in the ………. direction to try to reduce the temperature by absorbing heat

A

ENDOTHERMIC

19
Q

The larger the Kc the …….. the amount of products. If Kc is small we say the equilibrium favours the ……..

A

greater the products

if small eq favours reactants

20
Q

What happens if you increase the concentration of a reactant?

A

The equilibrium tries to remove extra rectant by producing more product and shifts RIGHT

21
Q

What happens if you decrease the concentration of a product?

A

Equilibrium tries to remove extra product by producing more reactant (reverse reaction faster) so eq shifts to the left

22
Q

What type of system is Kc relevant for?

A

Homogenous systems in equilibrium