thermodynamics Flashcards

1
Q

energy must be conserved.. but..

A

can take different forms

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2
Q

entropy

A

a measure of a systems disorder and tends to increase

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3
Q

what is free energy change determined by

A

the change in enthalpy and entropy

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4
Q

free energy must be negative…

A

for a reaction to be spontaneous

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5
Q

what are: open systems that constantly exchanged matter and energy with their surroundings

A

organisms

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6
Q

what do enzymes do

A

increase the rates of thermodynamically favourable reactions

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7
Q

the universe can be divided into two sections

A

system

everything else

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8
Q

system

A

what can be controlled

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9
Q

everything else

A

the surroundings

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10
Q

closed system

A

only allows energy and work

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11
Q

isolated systems

A

no transfer of matter, energy or work across boundary

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12
Q

open systems

A

transfer of matter, energy and work across the boundary

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13
Q

we usually use..

A

closed system, where only work and energy can cross the boundary

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14
Q

whether a reaction absorb or releases hat cannot predict…

A

whether the reaction will happen or not, therefore we must look to entropy

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15
Q

first law of thermodynamics

A

‘energy can neither be created or destroyed’
-the change in the internal energy of a closed thermodynamic system is equal to the sum of work done on the system and the amount of heat energy supplied to the system.

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16
Q

the change in the internal energy of a closed thermodynamic system is equal to..

A

the sum of work done on the system and the amount of heat energy supplied to the system

17
Q

most spontaneous reactions…

A

release internal energy

18
Q

when a system undergoes change: but these into an equation: deltaU= Q-W

A

u= internal energy of the system; Q=heat put into the system, W= work done ; delta= indicates change

deltaU= Q-W
or
deltaU=U(final)- U(initial)

19
Q

second law of thermodynamics

A

the total entropy of any isolated thermodynamic system tends to increase over time

20
Q

entropy basics

A
  • measure of disorder of a system
  • the ‘ordileness’ of a system is related to how likely an arrangement is to happen by chancr–> the more ways this could happen by chance- the greater the disorder
21
Q

the higher the entropy

A

the more disordered

22
Q

part of the second law is the..

A

law of statistics- with enough molecules- stats become inevitable

23
Q

deltaG

A

gibbs free energy

24
Q

gibbs free energy

A

combines both the change in entropy in a closed system, and the disorder added to the environment by the hear into a single function

25
Q

gibbs equation

A

deltaG=deltaH-TdeltaS

26
Q

to be spontaneous a reaction deltaG must be..

A

negative or equal to zero

27
Q

how com life is well ordered and operates a long way from equilibrium

A

due to coupled reactions

28
Q

how do coupled reactions make life more ordered and predictable

A

extremely favourable reactions are coupled (free energy is much smaller than zero) with extremely unfavourable reactions (free energy is more than 0)
-relies on the reverse of the unfavourable reaction being very slow in the cell

29
Q

example of where cells maintains pools of accessible, favourable reactions that can be used to drive other reactions

A

eg. the hydrolysis of ATP= -31jKmol-1