Thermodynamics Flashcards

1
Q

thermo

A

heat

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2
Q

dynamics

A

movement

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3
Q

enthalpy

A

heat energy
bonds breaking and forming

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4
Q

entropy

A

molecular organization
order vs disorder

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5
Q

combustion reaction

A

fire

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6
Q

products of a combustion reacion

A

CO2 and H2O
heat and disorder

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7
Q

DG0

A

standard change in free energy
located at the bottom of the curve

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8
Q

if delta G is POSITIVE, do we have more products or reactants

A

reactants

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9
Q

if delta G is NEGATIVE, do we have more products or reactants

A

products

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10
Q

relationship between DG0 and Keq

A

DG0 = -RT ln Keq
temp is in Kelvin

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11
Q

gas constant (R)

A

8.315 J/K*mol

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12
Q

henderson hasselbclch equation

A

pH = pKa + log [-An]/[HAn]

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13
Q

gibbs free energy equation

A

delta G = DG0 + RT ln ([C][D])/([A][B])

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14
Q

negative delta G

A

spontaneous

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15
Q

positive delta G

A

non-spontaneous

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16
Q

the ln of a number less than 1 =

A

negative

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17
Q

move delta G to the left =

A

more negative

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18
Q

move delta G to the right =

A

more positive

19
Q

the ln of 1 =

A

0

20
Q

the ln of a number greater than 1 =

A

positive

21
Q

energy =

A

heat + disorder

22
Q

two reasons a reaction can occur

A

the rearrangement of bonds leads to a release of excess energy as heat
the reaction leads to a greater state of disorder

23
Q

delta G =

A

delta H - (T)delta S

24
Q

delta H

A

heat in K
enthalpy

25
Q

delta S

A

entropy
disorder

26
Q

for delta G to be negative

A

delta H - (T)delta S must be NEGATIVE

27
Q

a large negative delta H means

A

the release of excess bond energy as heat (exothermic)

28
Q

a large positive delta S means

A

a significant increase in the state of disorder

29
Q

negative delta H menas

A

exothermic

30
Q

positive delta S means

A

greater disorder

31
Q

positive delta H means

A

endothermic

32
Q

negative delta S means

A

greater order

33
Q

delta G is positive when

A

positive delta H and negative delta S
= POSITIVE DELTA G

34
Q

reactions tend to occur in a way that dissipates energy and leads to an

A

increased disorder

35
Q

place where F and C are the same

A

-40 degrees

36
Q

change in bond energy between products and reactants

A

enthalpy

37
Q

spreading and sharing of thermal energy in a system is

A

entropy

38
Q

weaker bonds = _____ = _____

A

less stable, higher potential energy

39
Q

stronger bonds = _____ = _____

A

more stable, lower potential energy

40
Q
  • delta H
A

exothermic

41
Q

+ delta H

A

endothermic

42
Q

C to K

A

C + 273.15

43
Q

positive delta G0 (to the left) =

A