Thermodynamics Flashcards

1
Q

thermo

A

heat

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2
Q

dynamics

A

movement

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3
Q

enthalpy

A

heat energy
bonds breaking and forming

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4
Q

entropy

A

molecular organization
order vs disorder

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5
Q

combustion reaction

A

fire

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6
Q

products of a combustion reacion

A

CO2 and H2O
heat and disorder

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7
Q

DG0

A

standard change in free energy
located at the bottom of the curve

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8
Q

if delta G is POSITIVE, do we have more products or reactants

A

reactants

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9
Q

if delta G is NEGATIVE, do we have more products or reactants

A

products

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10
Q

relationship between DG0 and Keq

A

DG0 = -RT ln Keq
temp is in Kelvin

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11
Q

gas constant (R)

A

8.315 J/K*mol

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12
Q

henderson hasselbclch equation

A

pH = pKa + log [-An]/[HAn]

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13
Q

gibbs free energy equation

A

delta G = DG0 + RT ln ([C][D])/([A][B])

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14
Q

negative delta G

A

spontaneous

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15
Q

positive delta G

A

non-spontaneous

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16
Q

the ln of a number less than 1 =

A

negative

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17
Q

move delta G to the left =

A

more negative

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18
Q

move delta G to the right =

A

more positive

19
Q

the ln of 1 =

20
Q

the ln of a number greater than 1 =

21
Q

energy =

A

heat + disorder

22
Q

two reasons a reaction can occur

A

the rearrangement of bonds leads to a release of excess energy as heat
the reaction leads to a greater state of disorder

23
Q

delta G =

A

delta H - (T)delta S

24
Q

delta H

A

heat in K
enthalpy

25
delta S
entropy disorder
26
for delta G to be negative
delta H - (T)delta S must be NEGATIVE
27
a large negative delta H means
the release of excess bond energy as heat (exothermic)
28
a large positive delta S means
a significant increase in the state of disorder
29
negative delta H menas
exothermic
30
positive delta S means
greater disorder
31
positive delta H means
endothermic
32
negative delta S means
greater order
33
delta G is positive when
positive delta H and negative delta S = POSITIVE DELTA G
34
reactions tend to occur in a way that dissipates energy and leads to an
increased disorder
35
place where F and C are the same
-40 degrees
36
change in bond energy between products and reactants
enthalpy
37
spreading and sharing of thermal energy in a system is
entropy
38
weaker bonds = _____ = _____
less stable, higher potential energy
39
stronger bonds = _____ = _____
more stable, lower potential energy
40
- delta H
exothermic
41
+ delta H
endothermic
42
C to K
C + 273.15
43
positive delta G0 (to the left) =