Thermodynamic Flashcards
Born Haber order
Heat of formation Heat of Atomization First Ionization Bond Dissassociation Electron Affinity Lattice Enthalpy
Always Spontaneuos
G: -
H: -
S: +
H-T:-
Never Spont
G: +
H: +
S: -
H-T: +
Spont at Low
G: -
H: +
S: +
H-T: - if T is large and + if t is small
Spont at High
G: +
H: -
S: -
H-T: + i fT is large and - if t is small
Enthalpy Chaneg
Products - reactants
Endothermic
Absorb
Enthalpy: Positvie
Exothermic
Release
Enthalpy: Negative
Bonds broken
Absorb
Bonds made
Release
Largest LAttice Enthakpy
Low Ionic Charge
High Ionic Radius
Specific Heat
the energy required to raise the temp of 1kg of substance by 1K
Free Energy
enthalpy change - entropy change
Average bond enthalpy
the energy change when one mole of a specific bond is broken or created (can only be used in gaseous state)
I kj
1000 Joule
Enthlpy
Bond broken - bonds made