Extra Info Flashcards
Diamond
- 4 carbon atoms
- hard and rigid structure
- high melting point and poor electrical conductivity
- tetrahedral array by covalent bonds
Graphite
- 3 carbon atoms
- layer structure
- covalently bonded in a trigonal planar array
- good lubricant bc of London forces between layers
C60
- MOLECULAR structure
- individual c atoms with covalent bonds
- hexagonal structure
Trigonal Planor
120
Trigonal Pyramidal
107
Trigonal Bipyramidal
90 and 120
Octahedron
90 and 180
Bent
104.5
Tetrahedral
109.5
Melting
Ionic: high
Metallic: in the middle
Covalent: low
Solubility
Ionic: dissolves in water and polar solutions
Metallic: generally don’t dissolve
Covalent: dissolve in non polar solutions
Conductivity
Ionic: Water solutions (electrolytes) (not solid state)
Metallic: Conduct well
Covalent: poorly or not at all
Other
Ionic: Strong crystal lattice
Metallic: luster and malleability
Covalent: weak crystal structure
Formal Charge
shows the favored structure
Sigma Bond
when covalent bond formed and two orbitals overlap head on
Pi Bond
formed when two parallel p orbitals overlap side on
Covalent Network Solids
have repeating network of covalent bonds that extends throughout the solid forming equivalent of one large molecule
- hard
- rigid
- high melting points
Allotropes
very different chemical structures of the same element
- oxygen, sulfur, phosphorous and carbon