Thermal Energy Flashcards
Pressure
Force per unit Area.
Internal Energy
The sum of the random distribution of kinetic and potential energies associated with the molecules of a system.
Change of State
A change of state of a substance leads to a change in its Internal Energy but not its temperature.
Specific Heat Capacity
The quantity of thermal energy required to raise the temperature of a unit mass of the substance by a unit temperature rise.
Typically measured in Joules per kg per Kelvin (J kg-1 K-1).
Specific Latent Heat of Fusion
Quantity of energy per unit mass to change it at a constant temperature from a solid into a liquid.
Absolute Zero
The temperature at which a substance has minimum internal energy.
Boyles law
For a constant mass of gas at a constant temperature, the pressure exerted by the gas is inversely proportional to the volume it occupies.
P = constant/V
Charles’s law
For a constant mass of gas at a constant pressure, the volume occupied by the gas is proportional to its absolute temperature.
V = constant x T
Pressure law
For a constant mass of gas at a constant volume, the pressure exerted by the gas is proportional to its absolute temperature.
P = constant x T
Kinetic Theory of Gases Assumptions
- A gas contains a very large number of spherical particles (atoms or molecules).
- The forces between particles are negligible, except during collisions.
- The volume of the particles is negligible compared to the volume occupied by the gas.
- Most of the time a particle moves in a straight line at a constant velocity.
- The time of collision with each other, or the walls of the container is negligible compared with the time between collisions.
- The collisions of the particles with each other and with the container are perfectly elastic, so that no kinetic energy is lost.
Also, the mean translational KE of a particle of an ideal gas is proportional to the thermodynamic temperature.