Tests of Ions and Gases Flashcards
What is the only alkaline gas?
Ammonia (NH₃), which dissolves in water to form ammonium hydroxide (NH₄OH)
What gases are acidic?
- Chlorine: Cl₂ + H₂O → HCl + HOCl
- Sulfur dioxide: SO₂ + H₂O → H₂SO₃
- Nitrogen dioxide: NO₂ + H₂O → HNO₃
What are neutral gases?
H₂, O₂, He, and other non-metal gases that do not react with water
What happens when a non-metal oxide gas dissolves in water?
It forms an acid
Test for Hydrogen (H₂)
- Test: Approach with a lit splint
- Result: Burns with a “pop” sound
Test for Oxygen (O₂)
- Test: Insert a glowing splint
- Result: Splint relights
Test for Chlorine (Cl₂):
- Test: Pass gas through damp blue litmus paper
- Result: Litmus paper turns red, then bleaches
- Explanation: Cl₂ + H₂O forms HCl (turns red) and HOCl (bleaches)
Test for Carbon dioxide (CO₂):
- Test: Bubble gas through limewater
- Result: Limewater turns cloudy
- Explanation: Ca(OH)₂ + H₂O + CO₂ → CaCO₃ (white solid) + H₂O
Observation when excess CO₂ is added:
* Turns cloudy (CaCO₃ forms)
* Turns clear again (CaCO₃ dissolves to form Ca(HCO₃)₂)
Test for Water/Steam (H₂O)
- Test: Add anhydrous copper sulfate (white)
- Result: Turns blue (becomes hydrated)
Test for Ammonia (NH₃)
- Glass Tube Test: HCl + NH₃ → NH₄Cl (forms white gas)
- Litmus Paper Test: Turns damp red litmus paper blue
How is a flame test carried out?
- Wash platinum wire in HCl (to avoid contamination)
- Dip platinum wire into sample
- Insert into a non-luminous (clear) flame
- Observe flame color
Why use platinum wire for flame test?
- It is unreactive
- It has a high melting point
What are the colours of the flames for metals?
- Lithium (Li⁺): Red
- Potassium (K⁺): Lilac
- Sodium (Na⁺): Yellow
- Copper (Cu²⁺): Blue-green
- Calcium (Ca²⁺): Brick-red
What are the results for sodium hydroixide test?
- Iron (II) Fe²⁺: Green ppt
- Iron (III) Fe³⁺: Brown ppt
- Copper (II) Cu²⁺: Blue ppt
- Ammonium (NH₄⁺): No precipitate, but produces NH₃ gas when warmed (turns damp red litmus blue)
Carbonate (CO₃²⁻) Test:
- Test: Add HCl
- Result: Produces CO₂ bubbles that turn limewater cloudy
Sulfate (SO₄²⁻) Test:
- Test: Add HCl and barium chloride (acidified BaCl₂)
- Why add HCl? To remove carbonate impurities
- Result: White precipitate forms
Halide (Cl⁻, Br⁻, I⁻) Test:
- Test: Add nitric acid (HNO₃) and silver nitrate (AgNO₃)
- Why not use HCl? Cl⁻ would interfere with the test
Halide Ion Precipitate Color (results):
* Cl⁻: White ppt
* Br⁻: Cream ppt
* I⁻: Yellow ppt