Tests of Ions and Gases Flashcards

1
Q

What is the only alkaline gas?

A

Ammonia (NH₃), which dissolves in water to form ammonium hydroxide (NH₄OH)

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2
Q

What gases are acidic?

A
  • Chlorine: Cl₂ + H₂O → HCl + HOCl
  • Sulfur dioxide: SO₂ + H₂O → H₂SO₃
  • Nitrogen dioxide: NO₂ + H₂O → HNO₃
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3
Q

What are neutral gases?

A

H₂, O₂, He, and other non-metal gases that do not react with water

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4
Q

What happens when a non-metal oxide gas dissolves in water?

A

It forms an acid

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5
Q

Test for Hydrogen (H₂)

A
  • Test: Approach with a lit splint
  • Result: Burns with a “pop” sound
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6
Q

Test for Oxygen (O₂)

A
  • Test: Insert a glowing splint
  • Result: Splint relights
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7
Q

Test for Chlorine (Cl₂):

A
  • Test: Pass gas through damp blue litmus paper
  • Result: Litmus paper turns red, then bleaches
  • Explanation: Cl₂ + H₂O forms HCl (turns red) and HOCl (bleaches)
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8
Q

Test for Carbon dioxide (CO₂):

A
  • Test: Bubble gas through limewater
  • Result: Limewater turns cloudy
  • Explanation: Ca(OH)₂ + H₂O + CO₂ → CaCO₃ (white solid) + H₂O

Observation when excess CO₂ is added:
* Turns cloudy (CaCO₃ forms)
* Turns clear again (CaCO₃ dissolves to form Ca(HCO₃)₂)

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9
Q

Test for Water/Steam (H₂O)

A
  • Test: Add anhydrous copper sulfate (white)
  • Result: Turns blue (becomes hydrated)
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10
Q

Test for Ammonia (NH₃)

A
  • Glass Tube Test: HCl + NH₃ → NH₄Cl (forms white gas)
  • Litmus Paper Test: Turns damp red litmus paper blue
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11
Q

How is a flame test carried out?

A
  1. Wash platinum wire in HCl (to avoid contamination)
  2. Dip platinum wire into sample
  3. Insert into a non-luminous (clear) flame
  4. Observe flame color
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12
Q

Why use platinum wire for flame test?

A
  • It is unreactive
  • It has a high melting point
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13
Q

What are the colours of the flames for metals?

A
  • Lithium (Li⁺): Red
  • Potassium (K⁺): Lilac
  • Sodium (Na⁺): Yellow
  • Copper (Cu²⁺): Blue-green
  • Calcium (Ca²⁺): Brick-red
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14
Q

What are the results for sodium hydroixide test?

A
  • Iron (II) Fe²⁺: Green ppt
  • Iron (III) Fe³⁺: Brown ppt
  • Copper (II) Cu²⁺: Blue ppt
  • Ammonium (NH₄⁺): No precipitate, but produces NH₃ gas when warmed (turns damp red litmus blue)
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15
Q

Carbonate (CO₃²⁻) Test:

A
  • Test: Add HCl
  • Result: Produces CO₂ bubbles that turn limewater cloudy
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16
Q

Sulfate (SO₄²⁻) Test:

A
  • Test: Add HCl and barium chloride (acidified BaCl₂)
  • Why add HCl? To remove carbonate impurities
  • Result: White precipitate forms
17
Q

Halide (Cl⁻, Br⁻, I⁻) Test:

A
  • Test: Add nitric acid (HNO₃) and silver nitrate (AgNO₃)
  • Why not use HCl? Cl⁻ would interfere with the test

Halide Ion Precipitate Color (results):
* Cl⁻: White ppt
* Br⁻: Cream ppt
* I⁻: Yellow ppt