Organic (U1) Flashcards

1
Q

What are organic compounds?

A

Compounds that contain carbon and hydrogen. There are an infinite number of organic compounds.

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2
Q

What is a homologous series?

A

A group of organic compounds with:
* The same functional group
* The same general formula
* Similar chemical properties
* A gradual change in physical properties
* A difference of CH2 between consecutive members

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3
Q

What is a functional group?

A

An atom or group of atoms bonded in a specific arrangement that determines the chemical properties of a homologous series.

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4
Q

How do you name organic compounds?

A

Prefix: Based on the number of carbon atoms (Meth-1, Eth-2, Prop-3, But-4, etc.)

Suffix:
* Alkane: -ane
* Alkene: -ene
* Alcohol: -anol
* Carboxylic Acid: -anoic acid
* Ester: -yl…anoate

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5
Q

How does the number of carbons affect the volatility of organic compounds? (state)

A
  • 1-4 carbons: Gas
  • 5-15 carbons: Liquid
  • > 15 carbons: Solid
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6
Q

What are hydrocarbons?

A

Compounds made up of only hydrogen and carbon.

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7
Q

What are isomers?

A

Compounds with the same molecular formula but different displayed structures.

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8
Q

What is the general formula for alkanes?

A

CnH2n+2

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9
Q

What is an example of an alkane?

A

Pentane (C5H12)

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10
Q

How to get isomers of alkanes?

A

قص و الظق في النوص

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11
Q

What are the three reactions of alkanes?

A

Substitution: in the presence of halogens and UV light
* Example: CH4 + Br2 → CH3Br + HBr

Combustion: complete and incomplete
* Complete: Produces CO2 + H2O
* Incomplete: Produces CO + H2O (or soot if oxygen is very low)

Cracking: Breaking down large hydrocarbons into smaller, more useful alkanes and alkenes

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12
Q

What is the general formula for alkenes?

A

CnH2n

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13
Q

What makes alkenes unsaturated?

A

The presence of a C=C double bond.

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14
Q

How can you identify isomers of alkenes?

A

By moving the position of the double bond.

Example:
* But(1)ene → C=C-C-C
* But(2)ene → C-C=C-C

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15
Q

Why are double bonds reactive?

A

The unstable repulsion force between the two bonds makes them highly reactive.

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16
Q

What reactions do alkenes undergo?

A

Combustion (same as alkanes)

Addition reactions (breaking the double bond to add atoms):
* Hydrogenation: (+H2) → Forms an alkane (Requires Ni catalyst)
* Hydration: (+H2O) → Forms an alcohol (Requires H3PO4, 300°C, 65 atm, steam)
* Bromination: (+Br2) → Forms dibromo compounds (Orange bromine water turns colorless)

17
Q

What is crude oil?

A

A mixture of different alkanes.

18
Q

How is crude oil refined?

A

By fractional distillation, separating hydrocarbons based on boiling points.

19
Q

What are the fractions of crude oil (from most to least volatile)?

A
  • Refinery Gas
  • Gasoline (Petrol)
  • Kerosene (Paraffin)
  • Diesel
  • Fuel Oil
  • Bitumen
20
Q

What happens as you go down the fraction list?

A
  • Higher boiling point
  • More viscous
  • Darker color
  • Less flammable
  • Less volatile
  • Lower market demand and price
21
Q

What is cracking, and why is it important?

A
  • Definition: The breakdown of large hydrocarbons into smaller, more useful alkanes and alkenes.
  • Conditions: 600-700°C with a silica/alumina catalyst.
22
Q

How are alkenes made?

A
  1. Cracking of crude oil
  2. Dehydration of alcohols (Using H3PO4, 300°C, 65 atm)