Organic (U1) Flashcards
What are organic compounds?
Compounds that contain carbon and hydrogen. There are an infinite number of organic compounds.
What is a homologous series?
A group of organic compounds with:
* The same functional group
* The same general formula
* Similar chemical properties
* A gradual change in physical properties
* A difference of CH2 between consecutive members
What is a functional group?
An atom or group of atoms bonded in a specific arrangement that determines the chemical properties of a homologous series.
How do you name organic compounds?
Prefix: Based on the number of carbon atoms (Meth-1, Eth-2, Prop-3, But-4, etc.)
Suffix:
* Alkane: -ane
* Alkene: -ene
* Alcohol: -anol
* Carboxylic Acid: -anoic acid
* Ester: -yl…anoate
How does the number of carbons affect the volatility of organic compounds? (state)
- 1-4 carbons: Gas
- 5-15 carbons: Liquid
- > 15 carbons: Solid
What are hydrocarbons?
Compounds made up of only hydrogen and carbon.
What are isomers?
Compounds with the same molecular formula but different displayed structures.
What is the general formula for alkanes?
CnH2n+2
What is an example of an alkane?
Pentane (C5H12)
How to get isomers of alkanes?
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What are the three reactions of alkanes?
Substitution: in the presence of halogens and UV light
* Example: CH4 + Br2 → CH3Br + HBr
Combustion: complete and incomplete
* Complete: Produces CO2 + H2O
* Incomplete: Produces CO + H2O (or soot if oxygen is very low)
Cracking: Breaking down large hydrocarbons into smaller, more useful alkanes and alkenes
What is the general formula for alkenes?
CnH2n
What makes alkenes unsaturated?
The presence of a C=C double bond.
How can you identify isomers of alkenes?
By moving the position of the double bond.
Example:
* But(1)ene → C=C-C-C
* But(2)ene → C-C=C-C
Why are double bonds reactive?
The unstable repulsion force between the two bonds makes them highly reactive.
What reactions do alkenes undergo?
Combustion (same as alkanes)
Addition reactions (breaking the double bond to add atoms):
* Hydrogenation: (+H2) → Forms an alkane (Requires Ni catalyst)
* Hydration: (+H2O) → Forms an alcohol (Requires H3PO4, 300°C, 65 atm, steam)
* Bromination: (+Br2) → Forms dibromo compounds (Orange bromine water turns colorless)
What is crude oil?
A mixture of different alkanes.
How is crude oil refined?
By fractional distillation, separating hydrocarbons based on boiling points.
What are the fractions of crude oil (from most to least volatile)?
- Refinery Gas
- Gasoline (Petrol)
- Kerosene (Paraffin)
- Diesel
- Fuel Oil
- Bitumen
What happens as you go down the fraction list?
- Higher boiling point
- More viscous
- Darker color
- Less flammable
- Less volatile
- Lower market demand and price
What is cracking, and why is it important?
- Definition: The breakdown of large hydrocarbons into smaller, more useful alkanes and alkenes.
- Conditions: 600-700°C with a silica/alumina catalyst.
How are alkenes made?
- Cracking of crude oil
- Dehydration of alcohols (Using H3PO4, 300°C, 65 atm)