Strongly Basic Anion (SBA) Flashcards
What functional groups do SBA resins contain?
Quaternary ammonium compounds
SBA resins can be used with chloride or hydroxyl as exchange ions.
What ions do SBA resins remove when using hydroxyl as the exchange ion?
All anions
What ions do SBA resins remove when using chloride as the exchange ion?
Nitrate, sulphate, and several other ions
What is the operation reaction for chloride ion exchange?
2 Resin-Cl + SO42- → (Resin)2-SO4 + 2Cl
What is the regeneration reaction for chloride ion exchange?
Resin2-SO4 + 2NaCl → 2 Resin-Cl + Na2SO4
What is the operation reaction for hydroxyl ion exchange?
Resin-OH + NO3 → Resin-NO3 + OH-
What is the regeneration reaction for hydroxyl ion exchange?
Resin-NO3 + OH- → Resin-OH + NO3
What is used as the regeneration solution for hydroxyl ions?
Sodium hydroxide
What is used as the regeneration solution for chloride exchange ions?
Sodium chloride
Why are SBA resins with chloride exchange ions seldom used for brewing applications?
They have lower efficiency in removing alkalinity from feed water.
What are the three types of SBA resins?
Type I, Type II, and acrylic
Which type of SBA resin is more effective in removing silica?
Type I
What undesirable byproduct does Type I SBA resin produce?
Amine with a strong fishy smell
What happens to the pH of treated water when using hydroxyl ions?
Remains unchanged
What happens to the pH of treated water when using chloride ions?
Slight drop
What is the main function of WAC ion-exchange units?
Removes Ca²+ and Mg²+ associated with bicarbonate ions in alkaline conditions.
What is the regeneration chemical for SAC ion-exchange units?
NaCl, KCl, or strong acids (H2SO4 or HCl)
What is produced by WAC ion-exchange units?
CO2
In a serial ion-exchange system, what can be achieved by using SAC and WBA in series?
Full de-mineralisation (de-ionised water)
What is the benefit of using a mixed bed system?
Delivers excellent treated water quality
What is a drawback of mixed bed systems?
Difficult to regenerate
What water quality parameters can negatively affect ion exchange resins?
- High levels of free chlorine
- High salinity
- High or low temperatures
- High turbidity
- Excessively high or low pH
What factors determine the best resin for a particular application?
- Composition of incoming feed water quality
- Desired product water quality
- Availability and price of regenerant chemicals
- Existing water treatment system infrastructure
- Price of resins
- Nature of effluent produced by the resins