Solubility and Saturation Flashcards

1
Q

soluble

A

more than 1g of solute dissolves in 100 mL of solvent at room temperature

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2
Q

insoluble

A

less than 1g of solute dissolves in 100 mL of solvent at room temperature

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3
Q

what affects solutbility?

A
  • molecule size
  • ion charge and size
  • temperature
  • pressure
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4
Q

solubility

A

the quantity of solute that can dissolve in a gien quantity of solvent at a given temperature

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5
Q

how is solubility expressed?

A

as a maximum mass of solute that can be dissolved per 100g of solvent at a given temperature.

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6
Q

How does molecule size affect the solutbility of a covalent substance?

A

small molecules are often more soluble that larger molecules

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7
Q

most alkali metal compounds are soluble in water

A
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8
Q

solfide and phosphates are usually insoluble in water

A
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9
Q

How does the ion charge affect solubility?

A

soluble

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10
Q

smaller the ionic charge the more soluble a substance is, the larger the ionic charge the greater the force that holds ions together.

small ion charge = soluble
large ion charge = insoluble

A
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11
Q

smaller the ion NOT CHARGE, the stronger the force. compounds with small ions tend to be less soluble than those with large ions Why?

A

small ions bond more closely together than large ions, bunds between small ions is stronger than bond between large ions with same charge

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12
Q

How does temperature impact the solubility of solids?

A

solubility increases with temeperature, higher temperature means more energy to break the bonds

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13
Q

How does temperature impact the solubility of liquids?

A

not greatly affected by temperature, addtional energy to break bonds not needed

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14
Q

How does temperature impact the solubility of gases?

A

solubility of gases descreases with higher temperature

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15
Q

how to changes in pressure affect solubility for liquids and solids?

A

JK They don’t

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16
Q

How does pressure impact solubility of a gas

A

directly proportional to the pressure of gas above the liquid

think of pop bottle opening

17
Q

How does high pressure work wit gases?

A

when the gas is compressed, gas molecules enter the liquid more frequently so more are dissolved

18
Q

Diver + pressure

A
  • pressure increases the deeper you go
  • increased pressure causes the nitrogen in lungs to dissolve into the blood
  • as diver surfaces gas comes out of solution
    of surfaces too quixkly, can form bubbles in the blood
19
Q

saturated solution

A

a solution that contains the maximum quantity of solute at a given temperature

20
Q

unsaturated solution

A

a solution that contains less than the maximum quantity of solute

21
Q

supersaturated solution

A

force a solution to dissolve more solute than it normally would at a given temperature and pressure

22
Q

How do you achieve a supersaturated solution?

A

achieved by heating a solutionn, saturating it at a higher temperature then allowing it to cool.

23
Q

solubility curves of gases

A

GO DOWNNNNNN

gas particles have a lot of kinetic energy, when gas dissolves loses some of this energy, at higher temps the dissolved gas gains energy again and the gas comes out of the solution

24
Q

concentration definition

A

the ratio of the quantity of solute to the quantity of solution

25
Q

dilute solution

A

has a relatively small quantity of solute per unit volume of solution

26
Q

concentrated solution

A

has a relatively large quantity of solute per unit volume of solution

27
Q

2 ways a concentration of solution can be expressed

A
  • amount concentration (molar concentration)
  • percentage concentration
28
Q

amount concentration, molar concentration

A

expressed in units of mol/L

29
Q

old version

A

uses molarity

30
Q

percentage concentration 3 ways:

A

volume by volume
mass by volume
mass by mass (

31
Q

when is percentage volume by volume often used?

A

liquid in liquid solution
(v/v)

32
Q

when is percentage mass by volume most often used?

A

when a solid solute is dissolved in a liquid solvent (usually g/mL) (m/v)

33
Q

when is percentage mass per mass often used?

A

when a solid solute is dissolved in a solid solvent (m/m)

34
Q

parts per million (ppm)

A

1 part per million parts solution - 1: 10^6

35
Q

parts per billion (ppb)

A

1 part per billion parts solution - 1: 10^9

36
Q

parts per trillion(ppt)

A

1 part per trillion parts solution - 1: 10^12

37
Q

ppm, ppb, and ppt are

A

(m/m) ratios